Intercalation of alcohols into layered vanadyl phosphonates

Journal Article · Fri Oct 01 00:00:00 EDT 1993 · Journal of Solid State Chemistry; (United States)

DOI:https://doi.org/10.1006/jssc.1993.1314· OSTI ID:5117423

Gendraud, P; De Roy, M E; Besse, J P ^[1]

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1. Laboratoire de Physico-Chimie des Materiaux, Aubiere (France)

Layered vanadyl organophosphonates of general formula VO(RPO[sub 3]) nH[sub 2]O, where R = CH[sub 3], C[sub 2]H[sub 5], C[sub 6]H[sub 5], were synthesized in alcoholic solution. Intercalation of alkanols, C[sub n]H[sub 2n+1]OH (n = 1 - 4), and benzyl alcohol with each phosphonate previously prepared is reported and discussed. Samples and intercalation compounds were characterized for their X-ray powder diffraction patterns, IR spectra, and TGA analysis.

• OSTI ID: 5117423
• Journal Information: Journal of Solid State Chemistry; (United States), Journal Name: Journal of Solid State Chemistry; (United States) Vol. 106:2; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ABSORPTION SPECTROSCOPY
ALCOHOLS
CHALCOGENIDES
CHEMICAL ANALYSIS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CLATHRATES
COHERENT SCATTERING
DIFFRACTION
GRAVIMETRIC ANALYSIS
HYDROXY COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOSPHONATES
QUANTITATIVE CHEMICAL ANALYSIS
SCATTERING
SPECTROSCOPY
SYNTHESIS
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
X-RAY DIFFRACTION