Vanadyl benzylphosphonates and vanadyl naphthylphosphonates: Intercalation reactions with butanols

Journal Article · · Chemistry of Materials; (USA)

DOI:https://doi.org/10.1021/cm00008a024· OSTI ID:6902281

Johnson, J W; Brody, J F; Alexander, R M ^[1]; Pilarski, B; Katritzky, A R ^[2]

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1. Exxon Research and Engineering, Annandale, NJ (USA)
2. Univ. of Florida, Gainesville (USA)

Vanadyl organophosphonates of general formula VO(RPO{sub 3}){times} xH{sub 2}O {times} yC{sub 2}H{sub 5}OH have been synthesized by the reaction of V{sub 2}O{sub 5} with RPO{sub 3}H{sub 2} in refluxing ethanol (R = 1-naphthyl, 2-naphthyl, benzyl, p-chlorobenzyl, p-methylbenzyl, p-methoxybenzyl, {alpha}-methylbenzyl, 2,5-dimethylbenzyl, p-tert-butylbenzyl, benzoylmethyl, 1-naphthylmethyl, and 2-naphthylmethyl) and characterized by thermogravimetric analysis and x-ray powder diffraction. The new compounds exhibit layered structures that can be divided into groups according to the layer spacings observed.

• OSTI ID: 6902281
• Journal Information: Chemistry of Materials; (USA), Journal Name: Chemistry of Materials; (USA) Vol. 2:2; ISSN CMATE; ISSN 0897-4756
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360202 -- Ceramics
Cermets
& Refractories-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CATALYSTS
CHEMICAL ANALYSIS
COHERENT SCATTERING
DATA
DATA ANALYSIS
DIFFRACTION
EXPERIMENTAL DATA
GRAVIMETRIC ANALYSIS
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
OXYGEN COMPOUNDS
PHASE STUDIES
PHOSPHATES
PHOSPHORUS COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
SCATTERING
SYNTHESIS
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
VANADIUM PHOSPHATES
X-RAY DIFFRACTION