Raman spectroscopic and ab initio quantum chemical investigations of molecules and complex ions in the molten system CsCl-NbCl{sub 5}-NbOCl{sub 3}
- Norwegian Inst. of Technology, Trondheim (Norway)
CsCl-NbCl{sub 5}-NbOCl{sub 3} melts were studied by Raman spectroscopy for the temperature range 340 and 650{degrees}C. Bonding modes for Nb-O and various niobium anion species. Interpretations of the Raman spectra based on ab initio calculations were performed.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 508706
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 17 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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