Supported high efficiency polyolefin catalyst component and methods of making and using the same
A process is described for the polymerization of olefins. In this process, an alpha-olefin or a mixture of alpha-olefins under suitable reaction conditions is contacted with a catalyst system comprising a catalyst and a cocatalyst. The cocatalyst comprises an organometallic compound and the catalyst comprises a solid resulting from the interaction of reactants consisting essentially of a support base selected from magnesium and manganese dihalides. A second solid material is selected from aluminum trihalides, phosphorus trichloride, and phosphorus oxyrichloride. A first electron donor is selected from ethers and non-halogenated esters of carboxylic acids. The catalyst is prepared by co-comminuting the support base and the second solid material to form an anhydrous mixture, co-comminuting the anhydrous mixture with the first electron donor to form a catalyst support, and treating the catalyst support with, the transition metal compound.
- Assignee:
- Phillips Petroleum Co., Bartlesville, OK
- Patent Number(s):
- US 4618661
- OSTI ID:
- 5043931
- Resource Relation:
- Patent File Date: Filed date 12 Jul 1985
- Country of Publication:
- United States
- Language:
- English
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Supported polyolefin catalyst components and methods of making and using the same
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKENES
POLYMERIZATION
ALUMINIUM COMPOUNDS
ANHYDRIDES
BINDING ENERGY
CARBOXYLIC ACID ESTERS
CATALYST SUPPORTS
CATALYSTS
CHEMICAL COMPOSITION
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
COMMINUTION
ELECTRONS
ETHERS
MAGNESIUM COMPOUNDS
MANGANESE HALIDES
MIXTURES
PHOSPHORUS CHLORIDES
POLYOLEFINS
TRANSITION ELEMENT COMPOUNDS
VALENCE
ALKALINE EARTH METAL COMPOUNDS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
DISPERSIONS
ELEMENTARY PARTICLES
ENERGY
ESTERS
FERMIONS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
KINETICS
LEPTONS
MANGANESE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
PHOSPHORUS COMPOUNDS
POLYMERS
REACTION KINETICS
SYNTHESIS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)