IRRADIATION "FACTOR-DEPENDENCY." SOME VINYL MONOMERS: IRRADIATION CYCLE. Radiation Chemistry Laboratory Series Research Report No. 4
The effects of the dose, dose rate, irradiation cycle, and temperature are reported for the radioinduced polymerization of acrylonitrile, butyl acrylate, styrene, vinyl acetate, arylonitrile-- styrene mixtures, butyl acrylate- - styrene mixtures, vinyl acetate-- styrene mixtures, 1,1,3-trihydro perfluoropropyl acrylate, and 1, 1,7-trihydroperfluoroheptyl acrylate. It was concluded that: something more than a three-minute cycle at 75 deg C is the most efficient; the relative efficiency of a time cycle over continuous irradiation decreases with an increase in dose rate; efficiency decreases markedly at the higher dose rates; previous reaction rate formulations are not applicable; and the most desirable time cycle and temperature is a function of the monomer system. (B.O.G.)
- Research Organization:
- Quartermaster Research and Engineering Center, Natick, Mass.
- NSA Number:
- NSA-16-000201
- OSTI ID:
- 4837047
- Report Number(s):
- AD-256550
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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Related Subjects
ACRYLATES
ACRYLIC ACID
ALKYL RADICALS
BUTYL RADICALS
CHEMISTRY
CYANIDES
EFFICIENCY
FLUORINATED HYDROCARBONS
HALOGENATED HYDROCARBONS
HEPTYL RADICALS
IRRADIATION
MIXING
MONOMERS
NITRILES
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYMERIZATION
PROPYL RADICALS
RADIATION CHEMISTRY
RADIATION DOSES
REACTION KINETICS
STYRENE
TEMPERATURE
VINYL RADICALS