STUDIES OF ORGANO-ALKALI METAL COMPLEXES. PART V. THE REACTIVITIES AND VISIBLE SPECTRA OF COMPLEXES FORMED BY SOME ANILS, IMINES, HYDROCARBONS AND NITRO-COMPOUNDS

Journal Article · Tue May 01 00:00:00 EDT 1962 · Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II

DOI:https://doi.org/10.1039/tf9625800942· OSTI ID:4829032

Mathias, A; Warhurst, E

A number of complexes formed by alkali metals with some anils, imines, hydrocarbons, and aromatic nitrocompounds were prepared in dioxan solution. The relative reactivities towards organic halides of the sodium complexes were measured and the results compared with the values for other complexes. The linear relationship between the logarithm of the relative reactivity and orbital energy found previously is discussed further, The absorption spectra of the complexes in the visible region were determined. Further examples of a linear relationship between the frequencies of peak maxima and 1/(r/sub c/ + 2), where r/ sub c/ is the radius of the alkali metal cation, were found. (auth)

• Research Organization: Univ. of Manchester, Eng.
• NSA Number: NSA-16-020453
• OSTI ID: 4829032
• Journal Information: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II, Journal Name: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II Vol. Vol: 58; ISSN TFSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ABSORPTION
ALKALI METALS
AMINES
CHEMICAL REACTIONS
CHEMISTRY
DIOXANE
HALIDES
HYDROCARBONS
HYPERFINE STRUCTURE
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLICS
PREPARATION
SODIUM COMPLEXES
SOLVENTS
SPECTRA