STUDIES OF ORGANO-ALKALI AND ALKALINE EARTH METAL COMPLEXES. PART VI. THE REACTIVITY AND SPECTRA OF SOME ORGANO-ALKALINE EARTH METAL COMPLEXES

Journal Article · Tue May 01 00:00:00 EDT 1962 · Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II

DOI:https://doi.org/10.1039/tf9625800948· OSTI ID:4829031

Mathias, A; Warhurst, E

Methods for the preparation of alkaline earth metal complexes in dioxan are described. A preliminary attempt to define the extent of this field was made. The visible spectra and relative reactivities towards organic halides of the mono- benzophenone complexes were measured and the results compared with those for the corresponding alkali metal complexes. The linear relationahip between the logarithm of the relative reactivity and 1/(r/sub c/ + 2), (where r/sub c/ is the radius of the cation) which was found previously for alkali metal benzophenones is shown to hold for the alkaline earth metal benzophenones. (auth)

• Research Organization: Univ. of Manchester, Eng.
• NSA Number: NSA-16-020454
• OSTI ID: 4829031
• Journal Information: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II, Journal Name: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II Vol. Vol: 58; ISSN TFSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ALKALI METALS
ALKALINE EARTH METALS
BENZOPHENONE
CATIONS
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DIOXANE
HALIDES
KETONES
ORGANOMETALLICS
PHENYL RADICALS
PREPARATION
SOLVENTS
SPECTRA