STUDIES OF ORGANO-ALKALI AND ALKALINE EARTH METAL COMPLEXES. PART VII. THE EFFECT OF ENVIRONMENT ON THE VISIBLE SPECTRUM OF THE BENZOPHENONE FREE RADICAL ANION

Journal Article · Tue May 01 00:00:00 EDT 1962 · Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II

DOI:https://doi.org/10.1039/tf9625800953· OSTI ID:4839189

Powell, D G; Warhurst, E

The effect of added lithium bromide on the visible spectrum of the free radical anion of mono-lithium benzophenone in tetrahydrofuran was examined. The resuits indicated some form of clustering between the two species even at concertrations of less than 10/sup -3/ M-bar. The positions of the peak maximum of mono-alkali metal benzophenones in toluene, dimethoxyethane, and dimethyl formamide were measured. The results are discussed in terms of the solvating powers of the media. (auth)

• Research Organization: Univ. of Manchester, Eng.
• NSA Number: NSA-16-020455
• OSTI ID: 4839189
• Journal Information: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II, Journal Name: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II Vol. Vol: 58; ISSN TFSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ALKALI METALS
ALKALINE EARTH METALS
AMIDES
ANIONS
BENZOPHENONE
CHEMISTRY
COMPLEXES
ETHANE
FORMIC ACID
FREE RADICALS
FURANS
KETONES
LITHIUM BROMIDES
MEASURED VALUES
METHYL RADICALS
ORGANIC OXYGEN COMPOUNDS
ORGANOMETALLICS
OXYGEN COMPOUNDS
PHENYL RADICALS
QUANTITY RATIO
SPECTRA