Phase Equilibria in Fused Salt Systems: Binary Systems of Plutonium(III) Chloride with the Chlorides of Magnesium, Calcium, Strontium, and Barium
Journal Article
·
· Journal of Physical Chemistry
Thermal and differential thermal analysis techniques, supplemented by microscopic examination of cooled melts, were used to investigate phase equilibrium diagrams for the binary systems: PuCl/sub 3/-MgCl/sub 2/, Pu/Cl/sub 3/ -CaCl/sub 2/, PuCl/sub 3/SrCl/sub 2/, PuCl/sub 3/-BaCl/sub 2/. The PuCl/sub 3/- MgCl/sub 2/ and PuCl/sub 3/-CaCl/sub 2/ systems are characterized by single eutectic points: the PuCl/sub 3/-SrCl/sub 2/ and PuCl/sub 3/-BaCl/sub 2/ systems are characterized by peritectic transformations and solid solutions. Compounds of the tyne M/sub 3/PuCl/sub 9/ (M = Sr or Ba) are associated with the peritectic transformation and solid solutions occur in compositions which are rich in SrCl/ sub 2/ or BaCl/sub 2/.
- Research Organization:
- Univ. of New Mexico, Albuquerque; Los Alamos Scientific Lab., N. Mex.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-16-006419
- OSTI ID:
- 4820571
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 12 Vol. 65; ISSN 0022-3654
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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