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COORDINATION CHEMISTRY OF URANYL COMPOUNDS WITH PHOSPHO-ORGANIC DERIVATIVES CONTAINING GROUP P = O. PART II (in Russian)

Journal Article · · Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.)
OSTI ID:4810104
The molecular compositions of uranyl bromides, nitrates, and acetates, with tri-n-butylphosphinic oxide in solutions were determined. It is shown that molecular coordination of TBP and TBPO is identical and can be achieved through the phosphoryl oxygen. It is also shown that the uranyl coordination number in the Uo/sub 2/Br/sub 2/ (TBPO)/sub 2/ complex and in similar complexes with TBP is 4. The energy aspects of mutual addends in uranyl coordination are analyzed. (R.V.J.)
Research Organization:
Originating Research Org. not identified
NSA Number:
NSA-16-010034
OSTI ID:
4810104
Journal Information:
Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.), Journal Name: Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.) Vol. Vol: 3; ISSN RADKA
Country of Publication:
Country unknown/Code not available
Language:
Russian