CHARACTERISTICS OF INTERPHASE EQUILIBRIUM IN URANYL NITRATE EXTRACTION BY ORGANIC PHOSPHORUS DERIVATIVES CONSIDERING COMPONENT ACTIVITY COEFFICIENTS IN THE ORGANIC PHASE. III. EXTRACTION OF URANYL NITRATE BY TBP, DBBP, BDBP, AND TBPO MIXTURES WITH DILUENTS

Journal Article · Mon Dec 31 23:00:00 EST 1962 · Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.)

OSTI ID:4080778

Pushlenkov, M F; Shuvalov, O N

Solvent extraction of uranyl nitrate by TBP, DBBP, BDBP, and TBPO mixtures with chloroform, dichloroethane, and carbon tetrachloride was investigated. Extraction agent and diluent activity coefficients were estimated on the basis of diluent vapor pressure. An analysis was made of uranyl nltrnte distributions between TBP, DBBP, BDBP, and TBPO in chloroform, dichloroethane, and carbon tetrachloride and the aqueous phase, and effective extraction constants were determined. It was found that fewer ether oxygens in the extraction agent molecule result in an increased uranyl nitrate extraction, and that the diluent effect is exhibited in its reaction with uranyl nitrate extraction agent and disolvent. (R.V.J.)

• Research Organization: Originating Research Org. not identified
• NSA Number: NSA-18-013942
• OSTI ID: 4080778
• Journal Information: Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.), Journal Name: Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.) Vol. Vol: 5; ISSN RADKA
• Country of Publication: Country unknown/Code not available
• Language: Russian

Related Subjects

BUTYL PHOSPHATES
CARBON TETRACHLORIDE
CHELATES
CHEMISTRY
CHLOROFORM
CONFIGURATION
DBP
DIAGRAMS
DISTRIBUTION
ENERGY LEVELS
ETHANE
EXCITATION
MEASURED VALUES
METHYL RADICALS
MOLECULES
ORGANIC CHLORINE COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
OXYGEN
PHASE DIAGRAMS
PRESSURE
QUANTITY RATIO
SOLUTIONS
SOLVENT EXTRACTION
SOLVENTS
TBPO
THERMODYNAMICS
URANYL NITRATES
VAPORS
WATER