ON THE STRUCTURE OF COMPLEX URANYL COMPOUNDS

Technical Report · Sat Oct 31 04:00:00 EST 1959

OSTI ID:4269639

Chernyaev, I I; Golovnya, V A

A number of complex uranyl compounds containing homogeneous cyclic addends were studied. The existence of three genetic families of complex uranyl corapounds was shown. Complex uranyl compounds with heterogeneous cyclic substitutes were synthesized and studied on the basis of the displacing capacity of the addends under investigation. Mixed oxalate complex uranyl compounds containing noncyclic addends were synthesized and studied, such as ureate, acetate, and thiocyanate groups. The investigations conducted showed that uranyl ion, in the compounds studied has the coordination number six. The analyzed addends forming a cycle according to the power of their reciprocal displacing capacity are aligned in series. Carbonate uranyl compounds are the only exceptions from L. A. Chugayev's rule of cycles in the chemistry of complex compounds, exceptions which are caused by the nature of both the formation of complexes and of the addends. (auth)

• Research Organization: U.S.S.R.
• NSA Number: NSA-13-006411
• OSTI ID: 4269639
• Report Number(s): A/CONF.15/P/2138
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ACETATES
CARBONATES
CHEMISTRY
COMPLEXES
CRYSTALS
CYANIDES
CYCLOALKANES
CYCLOALKENES
HETEROCYCLICS
IONS
LATTICES
MEASURED VALUES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXALATES
URANYL COMPOUNDS
UREA