VIBRATIONAL SPECTRA OF PARTIALLY DEUTERATED AND TRITIATED STIBINES
Journal Article
·
· Z. physik. Chem. (Frankfurt)
Using the quadratic potential energy constants for stibine and stibine-d/ sub 3/ obtained earlier, the harmonie vibrational wave numbers of all the partially deuterated and tritiated stibines were determined. Based on a first- order perturbation theory, the rotational distortion constants were obtained for these molecules. The molar thermodynamic properties of heat capacity, heat content, free energy, and entropy were calculated for 1 atm pressure for a rigid- rotor harmonic-oscillator approximation. The mean square amplitudes of vibrations were also computed from the vibrational frequencies and the force fields for 25 deg C. (auth)
- Research Organization:
- British Columbia Research Council, Vancouver, Canada
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-16-023705
- OSTI ID:
- 4806424
- Journal Information:
- Z. physik. Chem. (Frankfurt), Journal Name: Z. physik. Chem. (Frankfurt) Vol. Vol: 32
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
HARMONIC WAVE NUMBERS, ROTATIONAL DISTORTION CONSTANTS, AND THERMODYNAMIC PROPERTIES FOR PARTIALLY DEUTERATED AND TRITIATED MOLECULES OF THE TYPE XYZ$sub 2$ (X = N, P, or As Y, Z = H, D, or T)
MEAN AMPLITUDES OF VIBRATION AND THERMODYNAMIC FUNCTIONS OF TECHNETIUM HEXAFLUORIDE
Vibrational spectra, normal modes, force field, and barrier to inversion of phosphiran, phosphiran-1-d$sub 1$ and phosphiran-2,3-d$sub 4$
Journal Article
·
Sat Oct 01 00:00:00 EDT 1960
· J. Mol. Spectroscopy
·
OSTI ID:4123074
MEAN AMPLITUDES OF VIBRATION AND THERMODYNAMIC FUNCTIONS OF TECHNETIUM HEXAFLUORIDE
Journal Article
·
Sat Jun 01 00:00:00 EDT 1963
· Indian Journal of Pure and Applied Physics (India)
·
OSTI ID:4660974
Vibrational spectra, normal modes, force field, and barrier to inversion of phosphiran, phosphiran-1-d$sub 1$ and phosphiran-2,3-d$sub 4$
Journal Article
·
Sat Sep 01 00:00:00 EDT 1973
· J. Mol. Struct., v. 18, no. 1, pp. 75-92
·
OSTI ID:4310051
Related Subjects
ANTIMONY HYDRIDES
CHEMISTRY
DEUTERIUM COMPOUNDS
ENERGY
ENTHALPY
ENTROPY
FIELD THEORY
FOURIER ANALYSIS
FREE ENERGY
FREQUENCY
HARMONIC ANALYSIS
MATHEMATICS
MOLECULES
NUMERICALS
OSCILLATIONS
PERTURBATION THEORY
QUANTITATIVE ANALYSIS
ROTATION
SPECIFIC HEAT
SPECTRA
THERMODYNAMICS
TRITIUM
VECTORS
WAVE MECHANICS
CHEMISTRY
DEUTERIUM COMPOUNDS
ENERGY
ENTHALPY
ENTROPY
FIELD THEORY
FOURIER ANALYSIS
FREE ENERGY
FREQUENCY
HARMONIC ANALYSIS
MATHEMATICS
MOLECULES
NUMERICALS
OSCILLATIONS
PERTURBATION THEORY
QUANTITATIVE ANALYSIS
ROTATION
SPECIFIC HEAT
SPECTRA
THERMODYNAMICS
TRITIUM
VECTORS
WAVE MECHANICS