HARMONIC WAVE NUMBERS, ROTATIONAL DISTORTION CONSTANTS, AND THERMODYNAMIC PROPERTIES FOR PARTIALLY DEUTERATED AND TRITIATED MOLECULES OF THE TYPE XYZ$sub 2$ (X = N, P, or As Y, Z = H, D, or T)
Journal Article
·
· J. Mol. Spectroscopy
OSTI ID:4123074
With the use of a harmonic potential energy function, the harmonic wave numbers for partially deuterated and tritiated molecules of the type XYZ/sub 2/(X = N, P, or As; Y, Z = H, D, or T) were calculated by the Wilson FG matrix method. The rotational distortion constants for all these molecules were calculated on the basis of the first-order perturbation theory of Kivelson and Wilson. With the calculated wave numbers, the molar thermodynamic prcperties were obtained for 12 temperatures between 100 and 1000 deg K for the ideal gaseous state at one atmosphere pressure and for a rigid-rotor harmonic-oscillator approximation. (auth)
- Research Organization:
- Illinois Inst. of Tech., Chicago
- NSA Number:
- NSA-15-001331
- OSTI ID:
- 4123074
- Journal Information:
- J. Mol. Spectroscopy, Journal Name: J. Mol. Spectroscopy Vol. Vol: 5
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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