ION EXCHANGE IN MIXED SOLVENTS. V. THE DISTRIBUTION OF HEXAVALENT URANIUM BETWEEN ALCOHOL-HYDROCHLORIC ACID SOLUTIONS AND THE STRONGLY BASIC ANION EXCHANGER DOWEX-1-MECHANISM OF URANIUM ADSORPTION

Journal Article · Fri Dec 01 00:00:00 EST 1961 · J. Inorg. & Nuclear Chem.

DOI:https://doi.org/10.1016/0022-1902(61)80284-4· OSTI ID:4793272

Tera, F; Korkisch, J

The influence of aliphatic alcohols upon the adsorption of uranium by the strongly basic anion exchanger Dowex-1 is examined. Equilibrium studies show that the adsorption of uranium as a chloride complex on the resin from solutions containing aliphatic alcohols and hydrochloric acid increases with the concentration and chain length of the alcohol, with decreasing dielectric constant of the medium and with increasing hydrochloric acid concentration. The structure of the adsorbed uranium complex is deduced from these resuits. (auth)

• Research Organization: Universitat, Vienna
• NSA Number: NSA-16-010109
• OSTI ID: 4793272
• Journal Information: J. Inorg. & Nuclear Chem., Vol. Vol: 20; Other Information: Orig. Receipt Date: 31-DEC-62
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

CHEMISTRY
ADSORPTION
ALCOHOLS
ANIONS
CHLORIDES
DIELECTRICS
DISTRIBUTION
HYDROCHLORIC ACID
ION EXCHANGE
JOURNAL
MIXING
REACTION KINETICS
RESINS
SEPARATION PROCESSES
SOLUTIONS
SOLVENT EXTRACTION
SOLVENTS
URANIUM
URANIUM COMPLEXES
URANYL COMPOUNDS