DEUTERIUM ISOTOPE EFFECTS IN THE OXIDATION OF ALDEHYDES WITH BROMINE

Journal Article · Thu Jan 31 23:00:00 EST 1963 · Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.

DOI:https://doi.org/10.1039/jr9630001303· OSTI ID:4727285

McTigue, P T; Sime, J M

The oxidation of aliphatic aldehydes with bromine exhibited a solvent isotope effect, k/sub h//k/sub d/ = 3.7. For benzaldehyde oxidation, k/sub h//k/ sub d/ = 1.3. The former involves reaction of the hydrate, the latter formation of a benzoyl cation. (auth)

• Research Organization: Univ. of Melbourne
• NSA Number: NSA-17-016037
• OSTI ID: 4727285
• Journal Information: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc., Journal Name: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.; ISSN JCSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ALDEHYDES
BROMINE
CHEMISTRY
COUPLING
CURIE POINT
DEUTERIUM
EXCITATION
FERMIONS
FERROMAGNETIC MATERIALS
INTERACTIONS
ISOTOPE EFFECTS
LATTICES
MAGNETISM
OXIDATION
QUANTUM MECHANICS
SECOND QUANTIZATION
SPIN
SPIN WAVES
STATISTICS
TEMPERATURE
THERMODYNAMICS