DEUTERIUM ISOTOPE EFFECTS IN SOME INTRAMOLECULAR AROMATIC SUBSTITUTIONS
Journal Article
·
· Journal of the American Chemical Society (U.S.)
S>2-(2-Deuteriophenyll-benzaldehyde (I) has been allowed to react with di-t-butyl peroxide to give fluorenone. An isotope effect, k/sub H/k/sub D/, of 1.38 was observed for this reaction. 2-(2-Deuteriophenyll-benzoyl peroxide (In has been cyclized by heating to give the lactone of 2carboxy-2'-hydroxybiphenyl (IIIa,b). An isotope effect of 1.32 for k/sub H/k/sub D/ was found for this reaction. Irradiation of 2-(2-deuteriophenyll-phenyldiazomethane (VI) gave fluorene. The isotope effect for this cyclization was found to be 1.12. (auth)
- Research Organization:
- Rutgers Univ., New Brunswick, N.J.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-12-012541
- OSTI ID:
- 4314604
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 80; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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Journal Article
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Sat Jul 05 00:00:00 EDT 1958
· Journal of the American Chemical Society (U.S.)
·
OSTI ID:4300443
DEUTERIUM ISOTOPE EFFECTS IN THE OXIDATION OF ALDEHYDES WITH BROMINE
Journal Article
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Thu Jan 31 23:00:00 EST 1963
· Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.
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OSTI ID:4727285
Secondary deuterium isotope effects for addition of nitrogen nucleophiles to substituted benzaldehydes
Journal Article
·
Tue Oct 30 23:00:00 EST 1973
· J. Amer. Chem. Soc., v. 95, no. 22, pp. 7369-7374
·
OSTI ID:4425481