Oxidation of aldehydes by chromium(VI) and by chromium(V) in 96% acetic acid
Journal Article
·
· Journal of the American Chemical Society
The chromic acid oxidation of benzaldehyde in 96% acetic acid had been found to produce chromium(V) as an intermediate. The rate constants for the chromium(VI) and chromium(V) oxidations were obtained for benzaidehyde as well as for substituted benzaldehydes, benzaldehyde-d, and a group of aliphatic aldehydes. The data are compared with the previously obtained data on the oxidation of benzaldehyde by chromium(VI) and the intermediate valence chromium species. (auth)
- Research Organization:
- Yale Univ., New Haven
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-29-024017
- OSTI ID:
- 4338738
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 6 Vol. 96; ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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