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SYSTEMATIC STUDY OF THE SOLVENT EXTRACTION OF METAL $beta$-DIKETONATES

Journal Article · · Analytica Chimica Acta (Netherlands)
The extraction of 30 metals (Be, Mg, Ca, Sr, Ba, Sc, La, Ti, Zr, Th, Cr, Mo, U, Mn, Co, Fe, Ni, Pd, Cu, Ag, Zn, Cd, Hg, Al, Ga, In, Tl, Sn, Pb, and Bi) by solutions of acetylacetone, benzoylacetone, and dibenzoylmethane in benzene was studied in relation to the pH values for extraction. The extraction constants and two-phase stability constants of the BETA -diketonates were calculated; these can be used to determine the optimum conditions for the separation of many metals. The linear relationship between the distributlon coefficients of BETA - diketones and their corresponding BETA -diketonates was confirmed. (auth)
Research Organization:
Faculty of Technical and Nuclear Physics, Prague
NSA Number:
NSA-17-020103
OSTI ID:
4718763
Journal Information:
Analytica Chimica Acta (Netherlands), Journal Name: Analytica Chimica Acta (Netherlands) Vol. Vol: 28; ISSN ACACA
Country of Publication:
Country unknown/Code not available
Language:
English

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