RADIATION INDUCED SOLID STATE COPOLYMERIZATION OF OXETANES

Journal Article · Mon Jul 01 00:00:00 EDT 1963 · J. Polymer Sci., Pt. B

DOI:https://doi.org/10.1002/pol.1963.110010715· OSTI ID:4694465

Hayashi, K; Watanabe, H; Okamura, S

The following four oxetanes were synthesized and copolymerized with each other by gamma radiation: 3,3bis(chloromethyl)oxetane (BCMO), 3-ethyl-3- chloromethyloxetane (ECMO), 3,3-bis (bromomethyl)oxetane (BBMO), and 3-ethyl-3- bromomethyloxetane (EBMO). Melting point measurements, differential thermal analysis, and x-ray diffraction analysis were carried out on monomer mixtures and copolymers for the following combinations: BCMOBBMO, BCMO-ECMO, ECMO-EBMO, BBMO- EBMO. Yields and compositions of the copolymers are plotted against mole fraction in monomer. (D.L.C.)

• Research Organization: Japanese Assn. for Radiation Research on Polymers, Osaka
• NSA Number: NSA-17-028988
• OSTI ID: 4694465
• Journal Information: J. Polymer Sci., Pt. B, Journal Name: J. Polymer Sci., Pt. B Vol. Vol: 1
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ALKENES
BROMINATED HYDROCARBONS
CHEMICAL REACTIONS
CHEMISTRY
DIFFRACTION
EXPANSION
GAMMA RADIATION
MEASURED VALUES
MELTING POINTS
METHYL RADICALS
METHYLENE RADICALS
MIXING
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
OXIDES
PHASE DIAGRAMS
POLYMERIZATION
POLYMERS
PREPARATION
QUALITATIVE ANALYSIS
RADIATION CHEMISTRY
THERMAL ANALYSIS
X RADIATION