MOSSBAUER RESONANCE EFFECTS IN IRON$sup 0$ ORGANOMETALLIC COMPLEXES
Journal Article
·
· Journal of the American Chemical Society (U.S.)
The Fe/sup 57/ Mossbauer resonance absorption results of a series of diene-- Fe(CO)/sub 3/ complexes and dienyl-- Fe(CO)/sub 3/ complex cations are reported. In common with most other Fe compounds, the Mossbauer spectra of these materials consist of two absorption lines of equal intensity. The diene- Fe(CO)/ sub 3/ complexes show strong quadrupole splitting and possess a chemical shift within the fairly narrow region delta = 0.2 plus or minus 0.025 mm/sec. The dienyl-- Fe(CO)/sub 3/ cationic complexes clearly form a separate group based upon their chemical shift, though they display roughly the same range of quadrupole splitting as seen in the diene-- Fe(CO)/sub 3/ complexes. (P.C.H.)
- Research Organization:
- Univ. of Texas, Austin
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-17-033895
- OSTI ID:
- 4652628
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 85; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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· Doklady Akademii Nauk SSSR (U.S.S.R.) English translation currently published in a number of subject-oriented journals
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OSTI ID:4633460
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Journal Article
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· Journal of Chemical Physics (U.S.)
·
OSTI ID:4773697
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Journal Article
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Sat Dec 14 23:00:00 EST 1963
· Journal of Chemical Physics (U.S.)
·
OSTI ID:4126183