Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Ruthenium-catalyzed hydrogen--deuterium exchange in alcohols. A convenient method for deuterium labeling of primary alcohols

Journal Article · · J. Org. Chem., v. 39, no. 2, pp. 260-261
Deuteration of primary alcohols in the C-1 position can be accomplished by adding deuterium oxide to a mixture of ruthenium catalyst and any one of the primary alcohols tested. The advantages of this procedure lie in its simplicity, its low cost, its avoidance of reactive oxidants and reductants, and its ability to be carried out under neutral pH. (LK)
Research Organization:
Marquette Univ., Milwaukee
Sponsoring Organization:
USDOE
NSA Number:
NSA-29-015361
OSTI ID:
4364029
Journal Information:
J. Org. Chem., v. 39, no. 2, pp. 260-261, Journal Name: J. Org. Chem., v. 39, no. 2, pp. 260-261; ISSN JOCEA
Country of Publication:
Country unknown/Code not available
Language:
English

Similar Records

On the mechanism of the ruthenium-catalyzed reconstitutive condensation of allylic alcohols and terminal alkynes
Journal Article · Wed Jul 01 00:00:00 EDT 1992 · Journal of the American Chemical Society · OSTI ID:229929

Direct Oxidation of Primary Alcohols to Carboxylic Acids
Journal Article · Wed Dec 16 23:00:00 EST 2020 · Synthesis · OSTI ID:1848897

Selective oxidation of primary alcohols to aldehydes by O/sub 2/ employing a trinuclear ruthenium carboxylate catalyst
Journal Article · Wed Jun 10 00:00:00 EDT 1987 · J. Am. Chem. Soc.; (United States) · OSTI ID:6137529