Direct Oxidation of Primary Alcohols to Carboxylic Acids

Cherepakhin, Valeriy; Williams, Travis J.

doi:10.1055/s-0040-1706102

Direct Oxidation of Primary Alcohols to Carboxylic Acids

Journal Article · Thu Dec 17 04:00:00 EST 2020 · Synthesis

DOI:https://doi.org/10.1055/s-0040-1706102· OSTI ID:1848897

^[1];

OSTI

Abstract

Oxidation of primary alcohols to carboxylic acids is a fundamental transformation in organic chemistry, yet despite its simplicity, extensive use, and relationship to pH, it remains a subject of active research for synthetic organic chemists. Since 2013, a great number of new methods have emerged that utilize transition-metal compounds as catalysts for acceptorless dehydrogenation of alcohols to carboxylates. The interest in this reaction is explained by its atom economy, which is in accord with the principles of sustainability and green chemistry. Therefore, the methods for the direct synthesis of carboxylic acids from alcohols is ripe for a modern survey, which we provide in this review.

1 Introduction

2 Thermodynamics of Primary Alcohol Oxidation

3 Oxometalate Oxidation

4 Transfer Dehydrogenation

5 Acceptorless Dehydrogenation

6 Electrochemical Methods

7 Outlook

Research Organization:: Univ. of Southern California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0008825

OSTI ID:: 1848897

Journal Information:: Synthesis, Journal Name: Synthesis Journal Issue: 06 Vol. 53; ISSN 0039-7881

Publisher:: Thieme

Country of Publication:: United States

Language:: English

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