TEMPERATURE AND PHASE EFFECTS ON THE PHOTOLYSIS OF ETHYL IODIDE

Technical Report · Tue Dec 31 23:00:00 EST 1957

DOI:https://doi.org/10.2172/4324962· OSTI ID:4324962

Luebbe, Jr, R H; Willard, J E

The elementary sieps in the photolysis of liquid ethyl iodide by light of wavelength 2537 A by determining initial rates of iodine production in the presence.of added iodine and hydrogen iodide were analyzed at 25 and --70 d C to get information on the activation energies of competing elementary reaciions. Investigations were also made of the effects of additives on the photolysis of glassy ethyl iodide at --180 d C, and evidence for the formation of trapped radicals during photolysis and radiolysis of the solid was sought by electron paramagnetic resonance measurements. (J.R.D.)

• Research Organization: Wisconsin. Univ., Madison
• NSA Number: NSA-12-013785
• OSTI ID: 4324962
• Report Number(s): AECU-3786
• Country of Publication: United States
• Language: English

Related Subjects

CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
ELECTRONS
ENERGY
ETHANE
ETHYL RADICALS
EXCITATION
FREQUENCY
HYDROIODIC ACID
IMPURITIES
IODIDES
IODINE
LIGHT
LOW TEMPERATURE
MAGNETIC RESONANCE
MAGNETISM
MEASURED VALUES
ORGANIC IODINE COMPOUNDS
PARAMAGNETISM
PHOTOLYSIS
RADIATION CHEMISTRY
RADIOLYSIS
REACTION KINETICS
TEMPERATURE
TRAPS