THE EXCHANGE REACTION BETWEEN SUBSTITUTED BENZYL IODIDES AND POTASSIUM IODIDE. X. m-CHLOROBENZYL IODIDE
Technical Report
·
OSTI ID:4276109
A measurable exchange was observed in methanol and ethanol between the iodine atom in m-chlorobenzyl iodide and the iodide ion in potassinm iodide. The exchange reaction was investigated over a temperature range from 0 to 31.0 C. The total iodide conceatration in methanol and in ethanol ranged from 0.00174 to 0.0115M and 0.00168 to O.OllOM, respectively. The rate laws for the exchange reactopm are R=2.0 x1-/sup 12//sub e//sup -17,000/RT/ 12//sub 3/ (m- ClBzI)(KI) in ethanol, where the units of R are moles x liter/sup -1/ x min/sup - 1/. (auth)
- Research Organization:
- New Mexico. Univ., Albuquerque
- DOE Contract Number:
- W-7405-ENG-26
- NSA Number:
- NSA-13-002724
- OSTI ID:
- 4276109
- Report Number(s):
- LA-2160UNM
- Country of Publication:
- United States
- Language:
- English
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