Multiple additions of Vaska-type iridium complexes to C{sub 60}. Preferential crystallization of the {open_quotes}para{close_quotes} double addition products C{sub 60}(Ir(CO)Cl(PMe{sub 3}){sub 2}){sub 2}{center_dot}2C{sub 6}H{sub 6} and C{sub 60}(Ir(CO)Cl(Pet{sub 3}){sub 2}){sub 2}{center_dot}C{sub 6}H{sub 6}
- Univ. of California, Davis, CA (United States); and others
The authors investigated addition of Vaska-type iridium complexes to C{sub 60} fullerene. Two products were observed and characterized: C{sub 60}(Ir(CO)Cl(PMe{sub 3}){sub 2}){sub 2}{center_dot}2C{sub 6}H{sub 6} and C{sub 60}(Ir(CO)Cl(PEt{sub 3}){sub 2}){sub 2}{center_dot}C{sub 6}H{sub 6}. These compounds were structurally characterized by X-ray crystallography and NMR spectroscopy. It is suggested that many isomers of the adducts are present in the reaction liquor, but low solubility of the observed products drives the observed distribution of solid products.
- OSTI ID:
- 420993
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 23 Vol. 33; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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