Directing effects in a fullerene epoxide addition. Formation and structural characterization of ({eta}{sup 2}-C{sub 60}O)Ir(CO)Cl(P(C{sub 6}H{sub 5}){sub 3}){sub 2}
- Univ. of California, Davis, CA (United States)
The authors report on the reaction of Ir(CO)Cl(PPh{sub 3}){sub 2}, 1, and C{sub 60}O. The focus here was to investigate the ability of O to direct addition of an iridium compound. The products were separated by liquid chromatography. X-ray diffraction and NMR was used in the characterization of the products. Two epoxide products were produced.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 450851
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 10 Vol. 33; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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