Spectroscopic study of dehydrochlorination and exchange with D{sub 2} in WH{sub 2}Cl{sub 2}(PMe{sub 2}Ph){sub 4}: Unexpected stereochemical rigidity of dodecahedra containing both hydride and chloride ligands. Crystal and molecular structure of W(H){sub 3}({eta}{sup 2}-C{sub 6}H{sub 4}PMe{sub 2})(PMe{sub 2}Ph){sub 3}
- Indiana Univ., Bloomington, IN (United States)
The H{sub 2} oxidative addition product, WH{sub 2}Cl{sub 2}L{sub 4}, has rigid stereochemistry and exchanges D{sub 2}. The authors investigated the mechanism of halide substitution. The crystal structure of an {beta}-hydrogen eliminated W(H){sub 3}({eta}{sup 2}-C{sub 6}H{sub 4}PMe{sub 2})(PMe{sub 2}Ph){sub 3}.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 420939
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 13 Vol. 33; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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