INFRARED SPECTRA OF URANYL NITRATE HYDRATE SOLUTIONS AT WATER DEFORMATION VIBRATION FREQUENCIES

Journal Article · Fri Jan 01 04:00:00 EST 1960 · Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.)

OSTI ID:4165857

Vdovenko, V M; Suglubov, D N; Smirnova, E A

Studies of spectral variations of uranyl nitrate dihydrate solutions in certain organic diluents and of uranyl nitrate ether solutions with various water concentrations indicated polarization of the coordinated uranium--water, formation of a hydrogen bond between hydrate and diluent molecules, and irregular positions of the first two and of the following water molecules in the coordination sphere. Comparisons of uranyl nitrate spectra in ethyl ether -CCl/ sub 4/, with various water concentrations, show that the hydration diminishes with increasing CCl/sub 4/ content as a result of greater water freedom and a second water solvation layer. The hydrogen bond between the hydrate and ether does not break even at very high concentrations of CCl/sub 4/. (R.V.J.)

• Research Organization: Originating Research Org. not identified
• NSA Number: NSA-14-021469
• OSTI ID: 4165857
• Journal Information: Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.), Journal Name: Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.) Vol. Vol: 2; ISSN RADKA
• Country of Publication: Country unknown/Code not available
• Language: Russian

Related Subjects

BONDING
CARBON TETRACHLORIDE
CHEMISTRY
ETHERS
HYDROGEN
INFRARED RADIATION
POLARIZATION
SOLUTIONS
SPECTRA
URANYL NITRATES
WATER