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THE MEAN-SQUARE AMPLITUDES OF INTERATOMIC DISTANCES IN HEXAFLUORIDE MOLECULES

Journal Article · · J. Mol. Spectry.
Possible values of force constants were estimated by using fundamental frequencies and a general quadratic potential function for hexafluorides of S, Se, Te, Mo, W, Re, Os, Ir, Pt, U, Np, and Pu. The root-mean-square amplitudes of interatomic distances were calculated from the force constants and fundamental frequencies. According to the mangnitudes of root-mean-square amplitudes hexafluoride molecules are classified into the following groups: SF/sub 6/, SeF/ sub 6/, and TeF/sub 6/ containing np electrons; molecules from MoF/sub 6/ to PtF/ sub 6/ containing 4d or 5d electrons; and UF/sub 6/, NpF/sub 6/, and PuF/sub 6/ containing 5f electrons. (auth)
Research Organization:
Nagoya Univ., Japan
NSA Number:
NSA-18-001639
OSTI ID:
4155347
Journal Information:
J. Mol. Spectry., Journal Name: J. Mol. Spectry. Vol. Vol: 11
Country of Publication:
Country unknown/Code not available
Language:
English

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