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Intermolecular interaction and induced-emission spectra of liquid activated systems. 5: Quantitative study of the influence of the mixed solvent composition on the lasing threshold of substituted phthalimides.

Journal Article · · Opt. Spectrosc. (USSR) (Engl. Transl.), v. 39, no. 2, pp. 175-178
OSTI ID:4122439
The spectral luminescence and lasing (lasing frequency, lasing threshold) parameters of 3- and 4-amino-N-methyl phthalimide in mixed nonpolar or weakly polar and polar solvents were compared with the values characterizing the intermolecular relaxation processes in the solution. It was demonstrated that, in accordance with concepts developed, a clear dependence of the threshold on the magnitude of the energy gap between the ground equilibrium and Franck--Condon electronic states of the activator molecule in the solution is observed: the greater the energy gap, the lower the lasing threshold, and vice versa. A preliminary evaluation of some experimental data that testify to the substantial effect of the statitistical intermolecular processes on the lasing parameters of multicomponent solutions is offered. (AIP)
Research Organization:
Originating Research Org. not identified
NSA Number:
NSA-33-016958
OSTI ID:
4122439
Journal Information:
Opt. Spectrosc. (USSR) (Engl. Transl.), v. 39, no. 2, pp. 175-178, Journal Name: Opt. Spectrosc. (USSR) (Engl. Transl.), v. 39, no. 2, pp. 175-178; ISSN OPSUA
Country of Publication:
United States
Language:
English