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Enhanced electron attachment to Rydberg states in molecular hydrogen volume discharges

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.370513· OSTI ID:337500
; ;  [1]; ;  [2];  [3]
  1. Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831-6122 (United States)
  2. Institute of Molecular Sciences, Academia Sinica, P.O. Box 23-166, Taipei 10764, Taiwan, Republic of (China)
  3. Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433 (United States)

We review recent studies on negative ion formation and studies in other areas that are relevant to the role of high-Rydberg states of H{sub 2} and H{sub 3} in hydrogen negative ion sources. Possible mechanisms for the formation of these excited states are discussed, including the formation of long-lived superexcited (core-excited) Rydberg states. Experimental evidence for negative ion formation via electron attachment to core-excited Rydberg states in a glow discharge apparatus is presented. An expression for the dissociative electron attachment rate constant for Rydberg molecules is derived based on electron capture by a Rydberg molecule due to polarization interaction. {copyright} {ital 1999 American Institute of Physics.}

OSTI ID:
337500
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 10 Vol. 85; ISSN JAPIAU; ISSN 0021-8979
Country of Publication:
United States
Language:
English

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