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In-situ monitoring of etch by-products during reactive ion beam etching of GaAs in chlorine/argon

Technical Report ·
DOI:https://doi.org/10.2172/292864· OSTI ID:292864
; ;  [1]; ; ; ;  [2]
  1. Florida Univ., Gainesville, FL (United States). Dept. of Materials Science and Engineering
  2. Sandia National Labs., Albuquerque, NM (United States)

Mass spectrometry of the plasma effluent during Reactive Ion Beam Etching (RIBE) of GaAs using an Inductively Coupled Plasma (ICP) source and a Cl{sub 2}/Ar gas chemistry shows that AsCl{sub 3}, AsCl{sub 2} and AsCl are all detected as etch products for As, while GaCl{sub 2} is the main signal detected for the Ga products. The variation in selective ion currents for the various etch products has been examined as a function of chuck temperature (30--100 C), percentage Cl{sub 2} in the gas flow, beam current (60--180 mA) and beam voltage (200--800 V). The results are consistent with AsCl{sub 3} and GaCl{sub 3} being the main etch product species under their conditions, with fragmentation being responsible for the observed mass spectra.

Research Organization:
Sandia National Labs., Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Management and Administration, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
292864
Report Number(s):
SAND--98-0223C; CONF-971201--; ON: DE98002588
Country of Publication:
United States
Language:
English

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