Influence of temperature on radiolysis of de-2-ethylhexyl sebacate

Journal Article · Wed Jan 01 00:00:00 EST 1992 · High Energy Chemistry

OSTI ID:263797

Oreshkova, N S; Saraeva, V V; Romantsev, M F ^[1]

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1. M.V. Lomonosov Moscow State Univ. (Russian Federation)

The influence of temperature on the radiolysis of di-2-ethylhexyl sebacate was studied. The yields of 2-ethylhexene and hydrogen are practically independent of the temperature in the range from 320 to 470 K. The yields of carbon dioxide, 2- ethylhexyl pelargonate, butyraldehyde, heptane and high boiling components increase inappreciably in the temperature range from 320 to 400 K: at temperatures higher than 400 K, the yields increase strongly. The yields of carbon monoxide and acid products increase linearly with increase in the temperature, while the yield of 2-ethylhexanol decreases. 5 refs., 2 figs., 1 tab.

• OSTI ID: 263797
• Journal Information: High Energy Chemistry, Vol. 25, Issue 4; Other Information: PBD: Jan 1992; TN: Translated from Khimiya Vysokikh Energii; 25: No. 4, 331-334(Jul-Aug 1991)
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
ESTERS
RADIOLYSIS
CHEMICAL REACTION YIELD
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE 0273-0400 K
TEMPERATURE RANGE 0400-1000 K