Hydrocracking of polyolefins over ceria-promoted Ni/BEA catalysts

Sun, Jessie A.; Selvam, Esun; Bregvadze, Alexander; Zheng, Weiqing; Vlachos, Dionisios G.

doi:10.1039/D5GC00345H

Hydrocracking of polyolefins over ceria-promoted Ni/BEA catalysts

Journal Article · Tue Dec 31 23:00:00 EST 2024 · Green Chemistry

DOI:https://doi.org/10.1039/D5GC00345H· OSTI ID:2537943

^[1]; Selvam, Esun ^[1]; Bregvadze, Alexander ^[2]; ^[2]; ^[3]

Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy St, Newark, DE 19716, USA, Center for Plastics Innovation, University of Delaware, 221 Academy St, Newark, DE 19716, USA
Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy St, Newark, DE 19716, USA
Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy St, Newark, DE 19716, USA, Center for Plastics Innovation, University of Delaware, 221 Academy St, Newark, DE 19716, USA, Delaware Energy Institute, University of Delaware, 221 Academy St, Newark, DE, 19716, USA

Ceria-promoted Ni/BEA catalysts exhibit enhanced naphtha productivity in LDPE hydrocracking. Ceria increases Ni dispersion, reducibility, hydrogenation ability, and suppresses coking.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0021166

OSTI ID:: 2537943

Journal Information:: Green Chemistry, Journal Name: Green Chemistry; ISSN GRCHFJ; ISSN 1463-9262

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (51)

X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M. Surface and Interface Analysis, Vol. 41, Issue 4 https://doi.org/10.1002/sia.3026	journal	April 2009
Interpretation of Ni2p XPS spectra of Ni conductors and Ni insulators Nesbitt, H. W.; Legrand, D.; Bancroft, G. M. Physics and Chemistry of Minerals, Vol. 27, Issue 5 https://doi.org/10.1007/s002690050265	journal	May 2000
CO2 Methanation in the Presence of Ce-Promoted Alumina Supported Nickel Catalysts: H2S Deactivation Studies Gac, Wojciech; Zawadzki, Witold; Rotko, Marek Topics in Catalysis, Vol. 62, Issue 5-6 https://doi.org/10.1007/s11244-019-01148-3	journal	February 2019
The stoichiometry of hydrogen and carbon monoxide chemisorption on alumina- and silica-supported nickel Bartholomew, C. Journal of Catalysis, Vol. 65, Issue 2 https://doi.org/10.1016/0021-9517(80)90316-4	journal	October 1980
Fourier transform infrared (DRIFT) investigation of glass-covered samples. Study of hydrogen spillover on zeolites Salzer, R.; Dressler, J.; Steinberg, K. -H. Vibrational Spectroscopy, Vol. 1, Issue 4 https://doi.org/10.1016/0924-2031(91)80005-9	journal	June 1991
Production, use, and fate of synthetic polymers Geyer, Roland Plastic Waste and Recycling: Environmental Impact, Societal Issues, Prevention, and Solutions, 13-32 https://doi.org/10.1016/B978-0-12-817880-5.00002-5	book	March 2020
X-ray diffraction study of nickel oxide reduction by hydrogen Richardson, J. Applied Catalysis A: General, Vol. 246, Issue 1 https://doi.org/10.1016/S0926-860X(02)00669-5	journal	June 2003
In situ FTIR spectra of pyridine adsorbed on SiO2–Al2O3, TiO2, ZrO2 and CeO2: general considerations for the identification of acid sites on surfaces of finely divided metal oxides Zaki, Mohamed I.; Hasan, Muhammad A.; Al-Sagheer, Fakhryia A. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 190, Issue 3 https://doi.org/10.1016/S0927-7757(01)00690-2	journal	October 2001
Comprehensive IR study on acid/base properties of metal oxides Tamura, Masazumi; Shimizu, Ken-ichi; Satsuma, Atsushi Applied Catalysis A: General, Vol. 433-434 https://doi.org/10.1016/j.apcata.2012.05.008	journal	August 2012
Effect of pretreatment conditions on acidity and dehydration activity of CeO2-MeOx catalysts Gnanamani, Muthu Kumaran; Garcia, Richard; Jacobs, Gary Applied Catalysis A: General, Vol. 602 https://doi.org/10.1016/j.apcata.2020.117722	journal	July 2020
Ceria-promoted Ni/SBA-15 catalysts for ethanol steam reforming with enhanced activity and resistance to deactivation Li, Di; Zeng, Liang; Li, Xinyu Applied Catalysis B: Environmental, Vol. 176-177 https://doi.org/10.1016/j.apcatb.2015.04.020	journal	October 2015
Reactivity descriptors for ceria in catalysis Capdevila-Cortada, Marçal; Vilé, Gianvito; Teschner, Detre Applied Catalysis B: Environmental, Vol. 197 https://doi.org/10.1016/j.apcatb.2016.02.035	journal	November 2016
Structure-activity relationship in hydrogenolysis of polyolefins over Ru/support catalysts Tamura, Masazumi; Miyaoka, Shuhei; Nakaji, Yosuke Applied Catalysis B: Environmental, Vol. 318 https://doi.org/10.1016/j.apcatb.2022.121870	journal	December 2022
A general strategy and a consolidated mechanism for low-methane hydrogenolysis of polyethylene over ruthenium Wang, Cong; Yu, Kewei; Sheludko, Boris Applied Catalysis B: Environmental, Vol. 319 https://doi.org/10.1016/j.apcatb.2022.121899	journal	December 2022
Efficient and selective dual-pathway polyolefin hydro-conversion over unexpectedly bifunctional M/TiO2-anatase catalysts Chen, Linxiao; Moreira, Julia B.; Meyer, Laura C. Applied Catalysis B: Environmental, Vol. 335 https://doi.org/10.1016/j.apcatb.2023.122897	journal	October 2023
IR investigation of the interaction of deuterium with Ce0.6Zr0.4O2 and Cl-doped Ce0.6Zr0.4O2 Gennari, F. C.; Montini, T.; Hickey, N. Applied Surface Science, Vol. 252, Issue 24 https://doi.org/10.1016/j.apsusc.2005.11.062	journal	October 2006
BEA zeolite supported Ce-promoted nickel catalysts for CO2 methanation Gac, Wojciech; Zawadzki, Witold; Słowik, Grzegorz Catalysis Today, Vol. 437 https://doi.org/10.1016/j.cattod.2024.114728	journal	July 2024
Unlocking naphtha from polyolefins using Ni-based hydrocracking catalysts Vance, Brandon C.; Yuliu, Zhifei; Najmi, Sean Chemical Engineering Journal, Vol. 487 https://doi.org/10.1016/j.cej.2024.150468	journal	May 2024
Catalytic processing of plastic waste on the rise Martín, Antonio J.; Mondelli, Cecilia; Jaydev, Shibashish D. Chem, Vol. 7, Issue 6 https://doi.org/10.1016/j.chempr.2020.12.006	journal	June 2021
The world of plastic waste: A review Nayanathara Thathsarani Pilapitiya, P. G. C.; Ratnayake, Amila Sandaruwan Cleaner Materials, Vol. 11 https://doi.org/10.1016/j.clema.2024.100220	journal	March 2024
Engineering non-noble Ni/WO_x-ZrO₂ towards boosted fuels production by catalytic upcycling of polyethylene at mild conditions Shang, Jingyuan; Li, Yan; Hu, Yiwen Journal of Catalysis, Vol. 430 https://doi.org/10.1016/j.jcat.2024.115302 115302	journal	February 2024
Cerium-promoted nickel catalysts supported on yttrium-doped γ-alumina for carbon dioxide methanation Battumur, Nyamsuren; Sergelenbaatar, Nomuunaa; Bold, Tungalagtamir Journal of CO2 Utilization, Vol. 68 https://doi.org/10.1016/j.jcou.2022.102380	journal	February 2023
Synthesis, structural and optical properties of CeO2 nanoparticles synthesized by a simple polyvinyl pyrrolidone (PVP) solution route Phoka, Sumalin; Laokul, Paveena; Swatsitang, Ekaphan Materials Chemistry and Physics, Vol. 115, Issue 1 https://doi.org/10.1016/j.matchemphys.2008.12.031	journal	May 2009
CO2 methanation on the catalyst of Ni/MCM-41 promoted with CeO2 Wang, Xiaoliu; Zhu, Lingjun; Liu, Yincong Science of The Total Environment, Vol. 625 https://doi.org/10.1016/j.scitotenv.2017.12.308	journal	June 2018
New interpretations of XPS spectra of nickel metal and oxides Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C. Surface Science, Vol. 600, Issue 9 https://doi.org/10.1016/j.susc.2006.01.041	journal	May 2006
Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design Wang, Haokun; Edman Tsang, Shik Chi Cell Reports Physical Science, Vol. 5, Issue 7 https://doi.org/10.1016/j.xcrp.2024.102075	journal	July 2024
Catalytic Upcycling of Polyolefins Sun, Jiakai; Dong, Jinhu; Gao, Lijun Chemical Reviews, Vol. 124, Issue 16 https://doi.org/10.1021/acs.chemrev.3c00943	journal	August 2024
Catalyzing the Hydrocracking of Low Density Polyethylene Bin Jumah, Abdulrahman; Anbumuthu, Vanithasri; Tedstone, Aleksander A. Industrial & Engineering Chemistry Research, Vol. 58, Issue 45 https://doi.org/10.1021/acs.iecr.9b04263	journal	October 2019
Shape-Selective Oriented Cerium Oxide Nanocrystals Permit Assessment of the Effect of the Exposed Facets on Catalytic Activity and Oxygen Storage Capacity Sreeremya, Thadathil S.; Krishnan, Asha; Remani, Kottayilpadi C. ACS Applied Materials & Interfaces, Vol. 7, Issue 16 https://doi.org/10.1021/acsami.5b00298	journal	April 2015
Hydrogenolysis Cleavage of the C_sp2–C_sp3 Bond over a Metal-Free NbOPO₄ Catalyst Zhou, Hao; Chen, Lu; Guo, Yong ACS Catalysis, Vol. 12, Issue 9 https://doi.org/10.1021/acscatal.2c00034	journal	April 2022
Disordered, Sub-Nanometer Ru Structures on CeO₂ are Highly Efficient and Selective Catalysts in Polymer Upcycling by Hydrogenolysis Chen, Linxiao; Meyer, Laura C.; Kovarik, Libor ACS Catalysis, Vol. 12, Issue 8 https://doi.org/10.1021/acscatal.2c00684	journal	April 2022
Role of Bifunctional Ru/Acid Catalysts in the Selective Hydrocracking of Polyethylene and Polypropylene Waste to Liquid Hydrocarbons Rorrer, Julie E.; Ebrahim, Amani M.; Questell-Santiago, Ydna ACS Catalysis, Vol. 12, Issue 22 https://doi.org/10.1021/acscatal.2c03596	journal	October 2022
Understanding the Structure–Activity Relationships in Catalytic Conversion of Polyolefin Plastics by Zeolite-Based Catalysts: A Critical Review Dong, Zhongwen; Chen, Wenjun; Xu, Keqing ACS Catalysis, Vol. 12, Issue 24 https://doi.org/10.1021/acscatal.2c04915	journal	November 2022
Ce-Promoted PtSn-Based Catalyst for Hydrocracking of Polyolefin Plastic Waste into High Yield of Gasoline-Range Products Wang, Haokun; Yoskamtorn, Tatchamapan; Zheng, Jianwei ACS Catalysis, Vol. 13, Issue 24 https://doi.org/10.1021/acscatal.3c03996	journal	November 2023
Size and Structure Effects of Carbon-Supported Ruthenium Nanoparticles on Waste Polypropylene Hydrogenolysis Activity, Selectivity, and Product Microstructure Sun, Jessie A.; Kots, Pavel A.; Hinton, Zachary R. ACS Catalysis, Vol. 14, Issue 5 https://doi.org/10.1021/acscatal.3c05927	journal	February 2024
Selective Hydrocracking of Waste Polyolefins toward Gasoline-Range Liquid Fuels via Tandem Catalysis over a Cerium-Promoted Pt/HY Catalyst Zhao, Pengcheng; Guo, Wenze; Gui, Zhipeng ACS Sustainable Chemistry & Engineering, Vol. 12, Issue 15 https://doi.org/10.1021/acssuschemeng.3c04163	journal	March 2024
Spillover in Heterogeneous Catalysis Conner, W. Curtis.; Falconer, John L. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a014	journal	May 1995
Converting Plastic Wastes to Naphtha for Closing the Plastic Loop Li, Lin; Luo, Hu; Shao, Zilong Journal of the American Chemical Society, Vol. 145, Issue 3 https://doi.org/10.1021/jacs.2c11407	journal	January 2023
Direct Neutron Spectroscopy Observation of Cerium Hydride Species on a Cerium Oxide Catalyst Wu, Zili; Cheng, Yongqiang; Tao, Franklin Journal of the American Chemical Society, Vol. 139, Issue 28 https://doi.org/10.1021/jacs.7b05492	journal	July 2017
Toward an Understanding of Selective Alkyne Hydrogenation on Ceria: On the Impact of O Vacancies on H ₂ Interaction with CeO ₂ (111) Werner, Kristin; Weng, Xuefei; Calaza, Florencia Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b10021	journal	November 2017
Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia Wang, Cong; Xie, Tianjun; Kots, Pavel A. JACS Au, Vol. 1, Issue 9 https://doi.org/10.1021/jacsau.1c00200	journal	August 2021
Intramolecular H/D Exchange of Ethanol Catalyzed by Acidic OH Groups on H-ZSM-5 Zeolite Yamazaki, Hiroshi; Yokoi, Toshiyuki; Tatsumi, Takashi The Journal of Physical Chemistry Letters, Vol. 5, Issue 20 https://doi.org/10.1021/jz5018625	journal	October 2014
Mechanistic classification and benchmarking of polyolefin depolymerization over silica-alumina-based catalysts Lee, Wei-Tse; van Muyden, Antoine; Bobbink, Felix D. Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-32563-y	journal	August 2022
Inverse ceria-nickel catalyst for enhanced C–O bond hydrogenolysis of biomass and polyether Zhao, Zelun; Gao, Guang; Xi, Yongjie Nature Communications, Vol. 15, Issue 1 https://doi.org/10.1038/s41467-024-52704-9	journal	September 2024
Defining quality by quantifying degradation in the mechanical recycling of polyethylene Patel, Arpan D.; Schyns, Zoé O. G.; Franklin, Thomas W. Nature Communications, Vol. 15, Issue 1 https://doi.org/10.1038/s41467-024-52856-8	journal	October 2024
Facile fabrication and photoelectrochemical properties of a one axis-oriented NiO thin film with a (111) dominant facet Kim, Chang Woo; Son, Young Seok; Pawar, Amol Uttam J. Mater. Chem. A, Vol. 2, Issue 46 https://doi.org/10.1039/C4TA03606A	journal	January 2014
An FTIR study of surface ceria hydroxy groups during a redox process with H2 Badri, Ahmed; Binet, Claude; Lavalley, Jean-Claude Journal of the Chemical Society, Faraday Transactions, Vol. 92, Issue 23 https://doi.org/10.1039/ft9969204669	journal	January 1996
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996
Plastic waste to fuels by hydrocracking at mild conditions Liu, Sibao; Kots, Pavel A.; Vance, Brandon C. Science Advances, Vol. 7, Issue 17 https://doi.org/10.1126/sciadv.abf8283	journal	April 2021
The Effects of Ce and W Promoters on the Performance of Alumina-Supported Nickel Catalysts in CO2 Methanation Reaction Gac, Wojciech; Zawadzki, Witold; Greluk, Magdalena Catalysts, Vol. 12, Issue 1 https://doi.org/10.3390/catal12010013	journal	December 2021
Recent Advances on Fine-Tuning Engineering Strategies of CeO2-Based Nanostructured Catalysts Exemplified by CO2 Hydrogenation Processes Varvoutis, Georgios; Lykaki, Maria; Marnellos, George E. Catalysts, Vol. 13, Issue 2 https://doi.org/10.3390/catal13020275	journal	January 2023

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