Electrochemical Os-mediated asymmetric dihydroxylation of olefins
Conference
·
OSTI ID:250109
- Okayama Univ. (Japan)
Recently, the effective chiral ligands for enantioselective dihydroxylation of olefins have intensively been investigated. Among the reported asymmetric dihydroxylation systems, the superiority of a H{sub 2}O/t-BuOH-K{sub 3}Fe(CN){sub 6}/K{sub 2}CO{sub 3} system with chiral ligands, i.e., DHQD and/or DHQ derivatives, has been mentioned. Herein, the authors disclose preliminary studies on the electrochemical Os-catalyzed asymmetric dihyroxylation of olefins with Sharpless` ligands (L*).
- OSTI ID:
- 250109
- Report Number(s):
- CONF-9508100--
- Country of Publication:
- United States
- Language:
- English
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