Temporally Stable Supramolecular Polymeric Salts Enabling High-Performance 3D All-Aromatic Polyimide Lattices

Weyhrich, Cody W.; Will, John W.; Nayyar, Garvit; Westover, Clarissa C.; Patterson, Steven; Arrington, Clay B.; Williams, Christopher B.; Long, Timothy E.

doi:10.1002/smll.202303188

Temporally Stable Supramolecular Polymeric Salts Enabling High-Performance 3D All-Aromatic Polyimide Lattices

Journal Article · Wed May 10 00:00:00 EDT 2023 · Small

DOI:https://doi.org/10.1002/smll.202303188· OSTI ID:2473196

^[1]; Will, John W. ^[2]; Nayyar, Garvit ^[1]; Westover, Clarissa C. ^[1]; Patterson, Steven ^[3]; Arrington, Clay B. ^[1]; Williams, Christopher B. ^[2]; ^[1]

Arizona State Univ., Tempe, AZ (United States)
Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Honeywell Federal Manufacturing and Technologies LLC, Kansas City, MO (United States)

Vat photopolymerization (VP) Additive Manufacturing (AM), in which UV light is selectively applied to cure photo-active polymers into complex geometries with micron-scale resolution, has a limited selection of aliphatic thermoset materials that exhibit relatively poor thermal performance. Ring-opening dianhydrides with acrylate-containing nucleophiles yielded diacrylate ester-dicarboxylic acids that enabled photo-active polyimide (PI) precursors, termed polysalts, upon neutralization with an aromatic diamine in solution. In situ FTIR spectroscopy coupled with a solution and photo-rheological measurements revealed a previously unknown time-dependent instability of 4,4'-oxydianiline (ODA) polysalts due to an aza-Michael addition. Replacement of the electron-donating ether-containing diamine with an electron withdrawing sulfone-containing monomer, e.g., 4,4'-diaminodiphenyl sulfone (DDS), prohibited the aza-Michael addition of the aromatic amine to the activated acrylate double bond. Novel DDS polysalt photocurable solutions are similarly analyzed and validated long-term stability, which enabled reproducible printing of polyimide organogel intermediates. Subsequent VP AM afforded 3-dimensional (3D) structures of intricate complexity and excellent surface finish, as demonstrated with scanning electron microscopy. In addition, the novel PMDA-HEA/DDS solution enabled the production of the first beam latticed architecture comprised of all-aromatic polyimide. Finally, the versatility of a polysalt platform for multi-material printing is further demonstrated by printing parts with alternating polysalt compositions.

View Accepted Manuscript (DOE)

Research Organization:: Kansas City Nuclear Security Campus (KCNSC), Kansas City, MO (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0002839

OSTI ID:: 2473196

Report Number(s):: NSC--614-4823

Journal Information:: Small, Journal Name: Small Journal Issue: 32 Vol. 19; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
additive manufacturing
all-aromatic polyimide
high-performance
photorheology
vat photopolymerization

Temporally Stable Supramolecular Polymeric Salts Enabling High-Performance 3D All-Aromatic Polyimide Lattices

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