Towards Long‐Term Stable Perovskite Solar Cells: Degradation Mechanisms and Stabilization Techniques

Ahn, Namyoung; Choi, Mansoo

doi:10.1002/advs.202306110

Towards Long‐Term Stable Perovskite Solar Cells: Degradation Mechanisms and Stabilization Techniques

Journal Article · Wed Nov 22 23:00:00 EST 2023 · Advanced Science

DOI:https://doi.org/10.1002/advs.202306110· OSTI ID:2470518

Ahn, Namyoung ^[1]; ^[2]

Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Seoul National Univ. (Korea, Republic of)

It is certain that perovskite materials must be a game‐changer in the solar industry as long as their stability reaches a level comparable with the lifetime of a commercialized Si photovoltaic. However, the operational stability of perovskite solar cells and modules still remains unresolved, especially when devices operate in practical energy‐harvesting modes represented by maximum power point tracking under 1 sun illumination at ambient conditions. This review article covers from fundamental aspects of perovskite instability including chemical decomposition pathways under light soaking and electrical bias, to recent advances and techniques that effectively prevent such degradation of perovskite solar cells and modules. In particular, fundamental causes for permanent degradation due to ion migration and trapped charges are overviewed and explain their interplay between ions and charges. Based on the degradation mechanism, recent advances on the strategies are discussed to slow down the degradation during operation for a practical use of perovskite‐based solar devices.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 2470518

Journal Information:: Advanced Science, Journal Name: Advanced Science Journal Issue: 4 Vol. 11; ISSN 2198-3844

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Scaling behavior of moisture-induced grain degradation in polycrystalline hybrid perovskite thin films Wang, Qi; Chen, Bo; Liu, Ye Energy & Environmental Science, Vol. 10, Issue 2 https://doi.org/10.1039/C6EE02941H	journal	January 2017
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Approaching the fill factor Shockley–Queisser limit in stable, dopant-free triple cation perovskite solar cells Stolterfoht, Martin; Wolff, Christian M.; Amir, Yohai Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/C7EE00899F	journal	January 2017
Interface passivation using ultrathin polymer–fullerene films for high-efficiency perovskite solar cells with negligible hysteresis Peng, Jun; Wu, Yiliang; Ye, Wang Energy & Environmental Science, Vol. 10, Issue 8 https://doi.org/10.1039/C7EE01096F	journal	January 2017
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A full overview of international standards assessing the long-term stability of perovskite solar cells Holzhey, Philippe; Saliba, Michael Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/C8TA06950F	journal	January 2018
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