From Defects to Degradation: A Mechanistic Understanding of Degradation in Perovskite Solar Cell Devices and Modules

Dunfield, Sean P.; Bliss, Lyle; Zhang, Fei; Luther, Joseph M.; Zhu, Kai; Hest, Maikel M.; Reese, Matthew O.; Berry, Joseph J.

doi:10.1002/aenm.201904054

From Defects to Degradation: A Mechanistic Understanding of Degradation in Perovskite Solar Cell Devices and Modules

Journal Article · Sat Feb 29 23:00:00 EST 2020 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201904054· OSTI ID:1660077

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Univ. of Colorado, Boulder, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States). Renewable and Sustainable Energy Inst.
National Renewable Energy Lab. (NREL), Golden, CO (United States). Renewable and Sustainable Energy Inst.

Metal halide perovskite solar cells (PSCs) have risen in efficiency from just 3.81% in 2009 to over 25.2% today. While metal halide perovskites have excelled in efficiency, advances in stability are significantly more complex and have progressed more slowly. The advance of efficiency, which is readily measured, over stability, which can require literally thousands of hours to demonstrate, is to be expected given the rapid rate of innovation in the field. In the face of changing absorber composition, synthetic approaches, and device stack components it is necessary to understand basic material properties to rationalize how to enable stability in devices. In this article the aim is to present an in-depth review of the current understanding of metal halide perovskite devices and module stability by focusing on what is known retarding intrinsic and extrinsic degradation mechanisms at the material, device, and module level. Once these considerations are presented the discussion then moves to connecting different degradation mechanisms to stresses anticipated in operation and how they can impact efficiency of cells and ultimately modules over time.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1660077

Alternate ID(s):: OSTI ID: 1602311

Report Number(s):: NREL/JA-5K00-75929; MainId:7055; UUID:ec0b4d58-e23e-ea11-9c2f-ac162d87dfe5; MainAdminID:14056

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 26 Vol. 10; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cubic or Orthorhombic? Revealing the Crystal Structure of Metastable Black-Phase CsPbI ₃ by Theory and Experiment Sutton, Rebecca J.; Filip, Marina R.; Haghighirad, Amir A. ACS Energy Letters, Vol. 3, Issue 8 https://doi.org/10.1021/acsenergylett.8b00672	journal	June 2018
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Understanding Degradation Mechanisms and Improving Stability of Perovskite Photovoltaics

Journal Article · Thu Nov 15 23:00:00 EST 2018 · Chemical Reviews · OSTI ID:1485569

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36 MATERIALS SCIENCE
perovskite defects
perovskite degradations
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From Defects to Degradation: A Mechanistic Understanding of Degradation in Perovskite Solar Cell Devices and Modules

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