Understanding Degradation Mechanisms and Improving Stability of Perovskite Photovoltaics

Boyd, Caleb C.; Cheacharoen, Rongrong; Leijtens, Tomas; McGehee, Michael D.

doi:10.1021/acs.chemrev.8b00336

Understanding Degradation Mechanisms and Improving Stability of Perovskite Photovoltaics

Journal Article · Thu Nov 15 23:00:00 EST 2018 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.8b00336· OSTI ID:1485569

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Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; Chulalongkorn Univ., Bangkok (Thailand). Metallurgy and Materials Science Research Inst.
Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; National Renewable Energy Lab. (NREL), Golden, CO (United States)
Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; Univ. of Colorado, Boulder, CO (United States). Dept. of Chemical and Biological Engineering

This review article examines the current state of understanding in how metal halide perovskite solar cells can degrade when exposed to moisture, oxygen, heat, light, mechanical stress, and reverse bias. It also highlights strategies for improving stability, such as tuning the composition of the perovskite, introducing hydrophobic coatings, replacing metal electrodes with carbon or transparent conducting oxides, and packaging. The article concludes with recommendations on how accelerated testing should be performed to rapidly develop solar cells that are both extraordinarily efficient and stable.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States); Stanford Univ., CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); US Office of Naval Research

Grant/Contract Number:: AC36-08GO28308; EE0008167

OSTI ID:: 1485569

Alternate ID(s):: OSTI ID: 1686151

Report Number(s):: NREL/JA--5K00-72914

Journal Information:: Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 5 Vol. 119; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures Khenkin, Mark V.; Katz, Eugene A.; Abate, Antonio Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.63659	text	January 2020

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