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Anion-Dependent Structure, Dehydration, and Hydroxide Ion Conductivity of Magnesium Aluminum Layered Double Hydroxides

Journal Article · · Chemistry of Materials
 [1];  [2];  [2];  [2];  [3]
  1. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States; OSTI
  2. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States
  3. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States; International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba 305-0044, Ibaraki, Japan

Not provided.

Research Organization:
Cornell Univ., Ithaca, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019445
OSTI ID:
2421316
Journal Information:
Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 16 Vol. 35; ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (41)

Layered double hydroxide composite membrane for advanced alkaline water electrolysis journal April 2022
Why Do Carbonate Anions Have Extremely High Stability in the Interlayer Space of Layered Double Hydroxides? Case Study of Layered Double Hydroxide Consisting of Mg and Al (Mg/Al = 2) journal August 2019
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies journal February 2022
Atomistic Insight into the Hydration States of Layered Double Hydroxides journal April 2022
Water Content and Particle Texture of Synthetic Hydrotalcite-like Layered Double Hydroxides journal February 1995
Recent Advances in Membrane-Based Electrochemical Hydrogen Separation: A Review journal February 2021
High ionic conductivity of Mg–Al layered double hydroxides at intermediate temperature (100–200°C) under saturated humidity condition (100% RH) journal July 2010
Rationally tuning host–guest interactions to free hydroxide ions within intertrimerically cuprophilic metal–organic frameworks for high OH conductivity journal January 2017
A highly conductive and robust anion conductor obtained via synergistic manipulation in intra- and inter-laminate of layered double hydroxide nanosheets journal January 2018
The Grotthuss mechanism journal October 1995
Constructing Fast Transmembrane Pathways in a Layered Double Hydroxide Nanosheets/Nanoparticles Composite Film for an Inorganic Anion-Exchange Membrane journal November 2022
Hydroxide ion conduction in Ni–Al layered double hydroxide journal April 2012
Evaluation of ionic conductivity for Mg–Al layered double hydroxide intercalated with inorganic anions journal June 2011
Layered double hydroxide membrane with high hydroxide conductivity and ion selectivity for energy storage device journal June 2021
A high-temperature anion-exchange membrane fuel cell journal October 2020
Fabrication of Mg-Al Layered Double Hydroxide Thin Membrane for All-Solid-State Alkaline Fuel Cell Using Glass Paper as a Support journal April 2020
Review of cell performance in anion exchange membrane fuel cells journal January 2018
Hofmeister Salt Effects on Surface Tension Arise from Partitioning of Anions and Cations between Bulk Water and the Air−Water Interface journal May 2007
Integrated inorganic membrane electrode assembly with layered double hydroxides as ionic conductors for anion exchange membrane water electrolysis journal January 2015
Hydrotalcite-type anionic clays: Preparation, properties and applications. journal December 1991
Zur Lehre von der Wirkung der Salze: Zweite Mittheilung journal February 1888
Single Layer 2D Crystals for Electrochemical Applications of Ion Exchange Membranes and Hydrogen Evolution Catalysts journal February 2019
Heating stage Raman and infrared emission spectroscopic study of the dehydroxylation of synthetic Mg-hydrotalcite journal January 2001
Superionic conduction along ordered hydroxyl networks in molecular-thin nanosheets journal January 2019
Infrared and Raman study of interlayer anions CO 3 2− , NO 3 , SO 4 2− and ClO 4 in Mg/Al-hydrotalcite journal May 2002
Hydroxide ion Conduction Mechanism in Mg-Al CO32− Layered Double Hydroxide journal May 2021
Influences of Cation Ratio, Anion Type, and Water Content on Polytypism of Layered Double Hydroxides journal June 2018
Single-layer nanosheets with exceptionally high and anisotropic hydroxyl ion conductivity journal April 2017
Positively Charged Nanosheets Derived via Total Delamination of Layered Double Hydroxides journal July 2005
In situ XRD and ATR-FTIR study on the molecular orientation of interlayer nitrate in Mg/Al-layered double hydroxides in water journal January 2007
Structural and Dynamical Nature of Hydration Shells of the Carbonate Ion in Water: An Ab Initio Molecular Dynamics Study journal January 2018
Quaternary Ammonium-Functionalized Polyethylene-Based Anion Exchange Membranes: Balancing Performance and Stability journal April 2023
Quaternized Graphene Oxide Nanocomposites as Fast Hydroxide Conductors journal February 2015
Interplay of Ion–Water and Water–Water Interactions within the Hydration Shells of Nitrate and Carbonate Directly Probed with 2D IR Spectroscopy journal July 2016
Unraveling the Hydroxide Ion Transportation Mechanism along the Surface of Two-Dimensional Layered Double Hydroxide Nanosheets journal January 2021
Recent progress on exploring exceptionally high and anisotropic H+/OH ion conduction in two-dimensional materials journal January 2018
Communication—Layered Double Hydroxide as Intermediate-Temperature Electrolyte for Efficient Water Splitting journal January 2020
Mg–Al layered double hydroxides: a correlation between synthesis-structure and ionic conductivity journal January 2014
A comprehensive review on the synthesis and applications of ion exchange membranes journal November 2021
Thermal Evolution of the Structure of a Mg−Al−CO 3 Layered Double Hydroxide:  Sorption Reversibility Aspects journal August 2004
Design and Synthesis of Hydroxide Ion–Conductive Metal–Organic Frameworks Based on Salt Inclusion journal January 2014

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