Selective Covalent Basal Plane Modification as a Probe of Hydroxide Ion Conduction Pathways in Magnesium Aluminum Layered Double Hydroxides

Dillenburger, Jarrett D.; Schulte, Leanna; Suleiman, Mohammed; Sheehan, Colton J.; Mallouk, Thomas E.

doi:10.1002/cssc.202400641

Selective Covalent Basal Plane Modification as a Probe of Hydroxide Ion Conduction Pathways in Magnesium Aluminum Layered Double Hydroxides (in EN)

Journal Article · Wed May 08 00:00:00 EDT 2024 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.202400641· OSTI ID:2575881

Dillenburger, Jarrett D. ^[1]; Schulte, Leanna ^[1]; Suleiman, Mohammed ^[1]; Sheehan, Colton J. ^[1]; ^[1]

Univ. of Pennsylvania, Philadelphia, PA (United States)

Understanding ionic conduction in layered double hydroxides (LDHs) is a crucial step towards utilizing them as solid, hydroxide ion‐conducting electrolytes in energy conversion applications. We selectively modified the interlayer and external surfaces of MgAl LDHs with tris(hydroxymethyl)aminomethane (TRIS) ligands. By adjusting the concentration of the TRIS surface modifier, the LDH basal plane surfaces could be functionalized everywhere (internally and externally) or only externally. External modification resulted in loss of OH‐conductivity compared to pristine LDHs, confirming that external platelet surfaces are the primary ion conduction pathway.

View Accepted Manuscript (DOE)

Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019445

Other Award/Contract Number:: DGE-1845298
NNCI-2025608

OSTI ID:: 2575881

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 18 Vol. 17; ISSN 1864-5631; ISSN 1864-564X

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: EN

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry
Science & Technology - Other Topics
hydroxide ion conductivity
intercalation
layered double hydroxide
surface ionic conductivity
surface modification

Selective Covalent Basal Plane Modification as a Probe of Hydroxide Ion Conduction Pathways in Magnesium Aluminum Layered Double Hydroxides (in EN)

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