Effect of relative humidity on the interlayer spacing of phosphate intercalated Mg, Al layered double hydroxide (hydrotalcite‐like) crystals

Reed, Titus; Wonderling, Nichole; Gevaudan, Juan Pablo; Mauro, John C.

doi:10.1111/jace.20178

Effect of relative humidity on the interlayer spacing of phosphate intercalated Mg, Al layered double hydroxide (hydrotalcite‐like) crystals

Journal Article · Fri Oct 04 00:00:00 EDT 2024 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.20178· OSTI ID:2458252

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Department of Materials Science and Engineering The Pennsylvania State University University Park Pennsylvania USA
Materials Research Institute The Pennsylvania State University University Park Pennsylvania USA
Department of Materials Science and Engineering The Pennsylvania State University University Park Pennsylvania USA, Department of Architectural Engineering The Pennsylvania State University University Park Pennsylvania USA

Abstract

The availability of water and the type of interlayer anions present affect the arrangement and interlayer spacing of layered double hydroxide (LDH). A systematic study of the effect of relative humidity (RH) on the basal spacing of phosphate intercalated, magnesium aluminum LDHs (MgAl–PO ₄ LDH) was conducted, confirming that MgAl‐PO ₄ LDH exhibit distinct interlayer spacing corresponding to separate low‐ and high‐hydration states produced when exposed to low and high humidity conditions. The transition from the low‐ to high‐hydration form begins when RH exceeds 33% and is accompanied by the transition from one to two interlayers of water. An improved understanding of the effect of RH on MgAl–PO ₄ LDHs will enable more accurate atomistic modeling and experimental characterization of MgAl–PO ₄ LDHs and may lead to improvements in the tunability of MgAl‐PO ₄ LDHs for commercial applications such as slow‐release fertilizer.

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Sponsoring Organization:: USDOE

OSTI ID:: 2458252

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 2 Vol. 108; ISSN 0002-7820

Publisher:: Wiley-BlackwellCopyright Statement

Country of Publication:: United States

Language:: English

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