Pillaring of layered double hydroxides (LDH's) by polyoxometalate anions

Journal Article · Wed May 25 00:00:00 EDT 1988 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00219a048· OSTI ID:6975309

Kwon, T; Tsigdinos, G A; Pinnavaia, T J

Layered silicate clays (LSC's) intercalated by pillaring polyoxocations are precursors to an important class of microporous catalysts for a large number of reactions, including shape selective petroleum cracking. To date, smectite clays are the only host structures known to be pillarable by purely inorganic oxo ions. In the present work they report the oxo ion pillaring of a new family of lamellar ionic compounds, namely the layered double hydroxides (LDH's).

• Research Organization: Michigan State Univ., East Lansing (USA)
• OSTI ID: 6975309
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 110:11; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020400 -- Petroleum-- Processing
36 MATERIALS SCIENCE
360602 -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ADSORPTION ISOTHERMS
CATALYSTS
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
DATA
EXPERIMENTAL DATA
HYDROGEN COMPOUNDS
HYDROXIDES
INFORMATION
ISOTHERMS
LAYERS
NUMERICAL DATA
OXYGEN COMPOUNDS
SORPTIVE PROPERTIES
SURFACE PROPERTIES
SYNTHESIS