Selective hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) over carbon supported copper catalysts using isopropyl alcohol as a hydrogen donor

Hsiao, Yung Wei; Zong, Xue; Zhou, Jiahua; Zheng, Weiqing; Vlachos, Dionisios G.

doi:10.1016/j.apcatb.2022.121790

Selective hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) over carbon supported copper catalysts using isopropyl alcohol as a hydrogen donor

Journal Article · Mon Jul 25 00:00:00 EDT 2022 · Applied Catalysis. B, Environmental

DOI:https://doi.org/10.1016/j.apcatb.2022.121790· OSTI ID:2418541

Hsiao, Yung Wei ^[1]; Zong, Xue ^[2]; Zhou, Jiahua ^[2]; Zheng, Weiqing ^[2]; Vlachos, Dionisios G. ^[2]

Univ. of Delaware, Newark, DE (United States); OSTI
Univ. of Delaware, Newark, DE (United States)

Selective hydrodeoxygenation (HDO) of 5-hydroxymethylfurfural to 2,5-dimethylfuran is of great importance. Here, we reveal a simple pathway for green and efficient HDO using readily available copper with in-situ hydrogen generation. A highly dispersed Cu/PBSAC catalyst consisting of small metallic Cu⁰ nanoparticles carries out isopropyl alcohol (IPA) dehydrogenation and subsequent HDO of HMF. Density functional theory calculations reveal that the dehydrogenation of IPA is more favorable on Cu(211) with a lower energy barrier of ~0.6 eV. This facet exists in a higher ratio on nanosized catalysts. Batch reactions using Cu/PBSAC at 190 °C exhibited 91.9% HMF conversion and 71.7% DMF selectivity in 6 hr, and > 96% DMF yield in 10 hr. The mechanical strength of the carbon support is ideal for continuous processing for increased productivity; we demonstrate a > 90% DMF yield at 1/WHSV of 2.4 hr. The process demonstrated here can be integrated with upstream HMF separation utilizing carbon adsorbents.

View Accepted Manuscript (DOE)

Research Organization:: American Institute of Chemical Engineers (AIChE), New York, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007888

OSTI ID:: 2418541

Alternate ID(s):: OSTI ID: 1879146

Journal Information:: Applied Catalysis. B, Environmental, Journal Name: Applied Catalysis. B, Environmental Journal Issue: C Vol. 317; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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