Comparison of HMF hydrodeoxygenation over different metal catalysts in a continuous flow reactor

Luo, Jing; Arroyo-Ramírez, Lisandra; Wei, Jifeng; Yun, Hongseok; Murray, Christopher B.; Gorte, Raymond J.

doi:10.1016/j.apcata.2015.10.009

Comparison of HMF hydrodeoxygenation over different metal catalysts in a continuous flow reactor

Journal Article · Thu Oct 22 00:00:00 EDT 2015 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2015.10.009· OSTI ID:1387337

Luo, Jing ^[1]; Arroyo-Ramírez, Lisandra ^[1]; Wei, Jifeng ^[1]; Yun, Hongseok ^[2]; Murray, Christopher B. ^[2]; Gorte, Raymond J. ^[1]

Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Chemical and Biomolecular Engineering
Univ. of Pennsylvania, Philadelphia, PA (United States)

The three-phase hydrodeoxygenation (HDO) of 5-hydroxymethylfurfural (HMF) and hydrogenation of 2,5-dimethylfuran (DMF) were studied over six carbon-supported metal catalysts (Pt, Pd, Ir, Ru, Ni, and Co) using a tubular flow reactor with 1-propanol solvent, at 180 °C and 33 bar. By varying the space time in the reactor, the reaction of HMF is shown to be sequential, with HMF reacting first to furfuryl ethers and other partially hydrogenated products, which then form 2,5-dimethylfuran (DMF). Ring-opened products and 2,5-dimethyltetrahydrofuran (DMTHF) were produced only from reaction of DMF. Rate constants for the pseudo-first-order sequential reactions were obtained for each of the metals. The selectivities for the reaction of DMF varied with the metal catalyst, with Pd forming primarily DMTHF, Ir forming a mixture of DMTHF and open-ring products, and the other metals forming primarily open-ring products. Catalyst stabilities followed the order Pt ~ Ir > Pd > Ni > Co > Ru. Since the stability order correlated with carbon balances in the product (>93% for Pt; <75% for Ru), deactivation appears to be caused by deposition of humins on the catalyst.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001004

OSTI ID:: 1387337

Alternate ID(s):: OSTI ID: 1250114

Journal Information:: Applied Catalysis. A, General, Journal Name: Applied Catalysis. A, General Journal Issue: C Vol. 508; ISSN 0926-860X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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A Non‐Noble Monometallic Catalyst Derived from Cu–MOFs for Highly Selective Hydrogenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran Zhang, Qingtu; Zuo, Jianliang; Peng, Feng ChemistrySelect, Vol. 4, Issue 46 https://doi.org/10.1002/slct.201903256	journal	December 2019
The H2 Pressure Dependence of Hydrodeoxygenation Selectivities for Furfural Over Pt/C Catalysts Luo, Jing; Monai, Matteo; Yun, Hongseok Catalysis Letters, Vol. 146, Issue 4 https://doi.org/10.1007/s10562-016-1705-x	journal	February 2016
Fundamentals of C–O bond activation on metal oxide catalysts Goulas, Konstantinos A.; Mironenko, Alexander V.; Jenness, Glen R. Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0234-6	journal	February 2019
A continuous flow process for the production of 2,5-dimethylfuran from fructose using (non-noble metal based) heterogeneous catalysis Braun, Max; Antonietti, Markus Green Chemistry, Vol. 19, Issue 16 https://doi.org/10.1039/c7gc01055a	journal	January 2017
Spectroscopic characterization of a highly selective NiCu ₃ /C hydrodeoxygenation catalyst Goulas, Konstantinos A.; Lee, Jennifer D.; Zheng, Weiqing Catalysis Science & Technology, Vol. 8, Issue 23 https://doi.org/10.1039/c8cy01280f	journal	January 2018
Synthesis of biomass-derived feedstocks for the polymers and fuels industries from 5-(hydroxymethyl)furfural (HMF) and acetone Chang, Hochan; Motagamwala, Ali Hussain; Huber, George W. Green Chemistry, Vol. 21, Issue 20 https://doi.org/10.1039/c9gc01859j	journal	January 2019
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