Mixed-ligand complexes of rare-earth elements with dipivaloylmethane and acetic acid
Journal Article
·
· Russian Journal of Coordination Chemistry
OSTI ID:240966
- Moscow State Univ. (Russian Federation); and others
Solids products forming in the MDpm{sub 3}-HAcet-n-hexane (M=Pr, Nd, Eu, Gd, Ho, Er, and Yb; HDpm is dipivaloylmethane; and HAcet is acetic acid) are characterized by the data or elemental, X-ray diffraction, and thermal analyses and IR spectroscopy. The resulting mixed-ligand complexes were found to have composition MDpm{sub 2}-Acet for all REEs studied. The difference in properties of the compounds of cerium and yttrium subgroups manifests itself in the thermal dissociation of the mixed-ligand complexes, which occurs under reduced pressure at 170{degrees}C.
- OSTI ID:
- 240966
- Journal Information:
- Russian Journal of Coordination Chemistry, Journal Name: Russian Journal of Coordination Chemistry Journal Issue: 11 Vol. 21; ISSN RJCCEY
- Country of Publication:
- United States
- Language:
- English
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