Phase Discovery and Selected Synthesis of Subvalent Niobium Tellurides Using a Polytelluride Flux Strategy

Sun, Fan; Yue, Haoyu; Puggioni, Danilo; Guo, Zhongnan; Li, Yutong; Rondinelli, James M.; Zhang, Zheng; Yuan, Wenxia; Kanatzidis, Mercouri G.

doi:10.1021/acs.inorgchem.3c01621

Phase Discovery and Selected Synthesis of Subvalent Niobium Tellurides Using a Polytelluride Flux Strategy

Journal Article · Tue Jul 25 00:00:00 EDT 2023 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.3c01621· OSTI ID:2397295

Sun, Fan ^[1]; Yue, Haoyu ^[1]; ^[2]; ^[3]; Li, Yutong ^[1]; ^[2]; ^[1]; ^[1]; ^[4]

Univ. of Science and Technology, Beijing (China)
Northwestern Univ., Evanston, IL (United States)
Univ. of Science and Technology, Beijing (China); Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Transition metal subchalcogenides involve electron-rich metals and can facilitate an in-depth understanding of the relationships among quantum properties such as superconductivity, charge density wave, and topological band structures. However, effective experimental routes toward synthesizing transition metal subchalcogenides are still lacking, hindering the development of new quantum materials. Herein, we propose a eutectic polytelluride flux strategy as an excellent solution to address phase discovery and crystal growth in transition metal subtelluride systems. We report new phases easily and selectively synthesized using a eutectic “K₃Te₄” polytelluride flux upon adjusting the ratio of Nb metal to flux in the starting materials (K/Nb/Te = 3:x:4). Using a high Nb content in the solvent (x = 2 and 1), crystals of KNb₃Te₃O_0.38 and K_0.9Nb₃Te₄ are obtained. Both subtellurides exhibit diverse Nb clusters, including face-sharing and edge-sharing Nb₆ octahedral columns and zig-zag Nb chains. Reducing the Nb content to x = 0.33 leads to the formation of a layered compound, K_1.06NbTe₂. This compound comprises a NbTe₆ trigonal prism with K intercalated between the layers. Single crystals of known binary Nb tellurides can also be grown using another eutectic flux “KTe₃.₂”, and the obtained NbTe₂ exhibits a new polymorphism with extra trimerization along the b-axis in the Nb–Nb bonded double zig-zag cluster. Finally, precise control over the structural dimensionality and oxidation state, combined with the facile crystal growth process, makes our synthetic strategy an efficient route to explore quantum materials in transition metal subchalcogenides.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2397295

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 31 Vol. 62; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (71)

From the Metal to the Molecule—Ternary Bismuth Subhalides Ruck, Michael Angewandte Chemie International Edition, Vol. 40, Issue 7 https://doi.org/10.1002/1521-3773(20010401)40:7<1182::aid-anie1182>3.0.co;2-b	journal	April 2001
Hard Radiation Detection from the Selenophosphate Pb ₂ P ₂ Se ₆ Wang, Peng L.; Liu, Zhifu; Chen, Pice Advanced Functional Materials, Vol. 25, Issue 30 https://doi.org/10.1002/adfm.201501826	journal	July 2015
Design of 2D Layered Catalyst by Coherent Heteroepitaxial Conversion for Robust Hydrogen Generation Sim, Yeoseon; Yoon, Aram; Kang, Hee Seong Advanced Functional Materials, Vol. 31, Issue 9 https://doi.org/10.1002/adfm.202005449	journal	December 2020
Van der Waals 2D Transition Metal Tellurides Su, Jianwei; Liu, Kailang; Wang, Fakun Advanced Materials Interfaces, Vol. 6, Issue 19 https://doi.org/10.1002/admi.201900741	journal	August 2019
Condensed Metal Clusters Simon, Arndt Angewandte Chemie International Edition in English, Vol. 20, Issue 1 https://doi.org/10.1002/anie.198100013	journal	January 1981
Clusters of Valence Electron Poor Metals—Structure, Bonding, and Properties Simon, Arndt Angewandte Chemie International Edition in English, Vol. 27, Issue 1 https://doi.org/10.1002/anie.198801591	journal	January 1988
The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds Kanatzidis, Mercouri G.; Pöttgen, Rainer; Jeitschko, Wolfgang Angewandte Chemie International Edition, Vol. 44, Issue 43 https://doi.org/10.1002/anie.200462170	journal	November 2005
Metal Anions in Metal-Rich Compounds and Polar Intermetallics Whangbo, Myung-Hwan; Lee, Changhoon; Köhler, Jürgen European Journal of Inorganic Chemistry, Vol. 2011, Issue 26 https://doi.org/10.1002/ejic.201100378	journal	July 2011
Analytic projection from plane-wave and PAW wavefunctions and application to chemical-bonding analysis in solids Maintz, Stefan; Deringer, Volker L.; Tchougréeff, Andrei L. Journal of Computational Chemistry, Vol. 34, Issue 29 https://doi.org/10.1002/jcc.23424	journal	September 2013
LOBSTER: A tool to extract chemical bonding from plane-wave based DFT: Tool to Extract Chemical Bonding Maintz, Stefan; Deringer, Volker L.; Tchougréeff, Andrei L. Journal of Computational Chemistry, Vol. 37, Issue 11 https://doi.org/10.1002/jcc.24300	journal	February 2016
Hydrogen Impurity Effects. A5Tt3 Intermetallic Compounds between A=Ca, Sr, Ba, Eu and Tt=Si, Ge, Sn with Cr5B3-like Structures that are Stable Both as Binary and as Ternary Hydride and Fluoride Phases Leon-Escamilla, E. Alejandro; Corbett, John D. Journal of Solid State Chemistry, Vol. 159, Issue 1 https://doi.org/10.1006/jssc.2001.9144	journal	June 2001
Die Kristallstruktur von TlFe3Te3 Klepp, Kurt; Boller, Herbert Monatshefte f�r Chemie, Vol. 110, Issue 3 https://doi.org/10.1007/bf00938371	journal	January 1979
Experimental Study of the Binary Nb-Te System de Lima, B. S.; Chaia, N.; Correa, L. E. Journal of Phase Equilibria and Diffusion, Vol. 40, Issue 5 https://doi.org/10.1007/s11669-019-00756-6	journal	September 2019
Superconductivity in the metallic layered compound NbTe2 Nagata, Shoichi; Abe, Tsuyoshi; Ebisu, Shuji Journal of Physics and Chemistry of Solids, Vol. 54, Issue 8 https://doi.org/10.1016/0022-3697(93)90215-d	journal	August 1993
Importance of short interlayer Te···Te contacts for the structural distortions and physical properties of CdI2-type layered transition-metal ditellurides Canadell, Enric; Jobic, Ste´phane; Brec, Raymond Journal of Solid State Chemistry, Vol. 99, Issue 1 https://doi.org/10.1016/0022-4596(92)90304-e	journal	July 1992
New compounds with infinite chains of face-condensed octahedral Mo6 Clusters: InMo3Se3, InMo3Te3, TlMo3Se3 and TlMo3Te3 Hönle, W.; Von Schnering, H. G.; Lipka, A. Journal of the Less Common Metals, Vol. 71, Issue 1 https://doi.org/10.1016/0022-5088(80)90109-5	journal	May 1980
New AxNb6Se8 (A = Na,K,Rb,Cu,Ag,Zn,Cd,Pb) phases with the Nb3Te4 structure Huan, G.; Greenblatt, M. Materials Research Bulletin, Vol. 22, Issue 4 https://doi.org/10.1016/0025-5408(87)90261-3	journal	April 1987
High-pressure synthesis of β-W-type Nb3Te Cannon, JohnF.; Robertson, DonaldL.; Hall, H. Tracy Solid State Communications, Vol. 15, Issue 1 https://doi.org/10.1016/0038-1098(74)90036-2	journal	July 1974
Superconductivity in the Nb cluster compounds Nb3(X,Y)4 with X, Y  S, Se, Te Amberger, E.; Polborn, K.; Grimm, P. Solid State Communications, Vol. 26, Issue 12 https://doi.org/10.1016/0038-1098(78)91258-9	journal	June 1978
Study of the metal-semiconductor transition in Rb2Mo6Se6, Rb2Mo6Te6 and Cs2Mo6Te6 under pressures Hor, P. H.; Fan, W. C.; Chou, L. S. Solid State Communications, Vol. 55, Issue 3 https://doi.org/10.1016/0038-1098(85)90722-7	journal	July 1985
FactSage thermochemical software and databases, 2010–2016 Bale, C. W.; Bélisle, E.; Chartrand, P. Calphad, Vol. 54 https://doi.org/10.1016/j.calphad.2016.05.002	journal	September 2016
A new low temperature modification of TaTe2—Comparison to the room temperature and the hypothetical 1T-TaTe2 modification Sörgel, T.; Nuss, J.; Wedig, U. Materials Research Bulletin, Vol. 41, Issue 5 https://doi.org/10.1016/j.materresbull.2006.02.020	journal	May 2006
Quantum linear magnetoresistance in NbTe 2 Chen, Hongxiang; Li, Zhilin; Fan, Xiao Solid State Communications, Vol. 275 https://doi.org/10.1016/j.ssc.2018.02.019	journal	July 2018
Synthesis, characterization, and electronic structure of KV3Te3O0.42 Wu, Eric J.; Pell, Michael A.; Genin, Hugh S. Journal of Alloys and Compounds, Vol. 278, Issue 1-2 https://doi.org/10.1016/s0925-8388(98)00585-4	journal	August 1998
New directions in synthetic solid state chemistry: chalcophosphate salt fluxes for discovery of new multinary solids Kanatzidis, M. Current Opinion in Solid State and Materials Science, Vol. 2, Issue 2 https://doi.org/10.1016/s1359-0286(97)80058-7	journal	April 1997
Casting a Wider Net: Rational Synthesis Design of Low-Dimensional Bulk Materials Benavides, Katherine A.; Oswald, Iain W. H.; Chan, Julia Y. Accounts of Chemical Research, Vol. 51, Issue 1 https://doi.org/10.1021/acs.accounts.7b00461	journal	December 2017
Clusters, Assemble: Growth of Intermetallic Compounds from Metal Flux Reactions Latturner, Susan E. Accounts of Chemical Research, Vol. 51, Issue 1 https://doi.org/10.1021/acs.accounts.7b00483	journal	December 2017
Local Distortions and Metal–Semiconductor–Metal Transition in Quasi-One-Dimensional Nanowire Compounds AV₃Q₃O_δ (A = K, Rb, Cs and Q = Se, Te) Guo, Zhongnan; Sun, Fan; Puggioni, Danilo Chemistry of Materials, Vol. 33, Issue 7 https://doi.org/10.1021/acs.chemmater.1c00434	journal	April 2021
Polymorphic Layered MoTe ₂ from Semiconductor, Topological Insulator, to Weyl Semimetal Sankar, Raman; Narsinga Rao, G.; Muthuselvam, I. Panneer Chemistry of Materials, Vol. 29, Issue 2 https://doi.org/10.1021/acs.chemmater.6b04363	journal	January 2017
van der Waals Metallic Transition Metal Dichalcogenides Han, Gang Hee; Duong, Dinh Loc; Keum, Dong Hoon Chemical Reviews, Vol. 118, Issue 13 https://doi.org/10.1021/acs.chemrev.7b00618	journal	June 2018
Bismuth—The Magic Element Kanatzidis, Mercouri; Sun, Hongzhe; Dehnen, Stefanie Inorganic Chemistry, Vol. 59, Issue 6 https://doi.org/10.1021/acs.inorgchem.0c00222	journal	March 2020
Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 56, Issue 6 https://doi.org/10.1021/acs.inorgchem.7b00188	journal	March 2017
Cs _0.9 Ni _3.1 Se ₃ : A Ni-Based Quasi-One-Dimensional Conductor with Spin-Glass Behavior Sun, Fan; Guo, Zhongnan; Liu, Ning Inorganic Chemistry, Vol. 57, Issue 7 https://doi.org/10.1021/acs.inorgchem.7b03143	journal	March 2018
Widespread Interstitial Chemistry of Mn ₅ Si ₃ -Type and Related Phases. Hidden Impurities and Opportunities Corbett, John D.; Garcia, Eduardo; Guloy, Arnold M. Chemistry of Materials, Vol. 10, Issue 10 https://doi.org/10.1021/cm980223c	journal	October 1998
Exploratory Synthesis in the Solid State. Endless Wonders ^† Corbett, John D. Inorganic Chemistry, Vol. 39, Issue 23 https://doi.org/10.1021/ic0007862	journal	November 2000
Synthesis, Crystal and Electronic Structures, and Properties of the New Pnictide Semiconductors A ₂ Cd Pn ₂ ( A = Ca, Sr, Ba, Eu; Pn = P, As) Wang, Jian; Yang, Min; Pan, Ming-Yan Inorganic Chemistry, Vol. 50, Issue 17 https://doi.org/10.1021/ic200286t	journal	September 2011
Stabilization by Hydrogen. Synthetic and Structural Studies of the Zintl Phase Ba ₅ Ga ₆ H ₂ Henning, Robert W.; Leon-Escamilla, E. Alejandro; Zhao, Jing-Tai Inorganic Chemistry, Vol. 36, Issue 7 https://doi.org/10.1021/ic9612966	journal	March 1997
Sodium tetramolybdenum hexoxide (NaMo4O6). A metallic infinite-chain polymer derived by condensation of octahedral clusters Torardi, Charlie C.; McCarley, Robert E. Journal of the American Chemical Society, Vol. 101, Issue 14 https://doi.org/10.1021/ja00508a043	journal	July 1979
Gadolinium sesquichloride, an unusual example of metal-metal bonding Lokken, Donald A.; Corbett, John D. Journal of the American Chemical Society, Vol. 92, Issue 6 https://doi.org/10.1021/ja00709a085	journal	March 1970
The Subchalcogenides Ir ₂ In ₈ Q (Q = S, Se, Te): Dirac Semimetal Candidates with Re-entrant Structural Modulation Khoury, Jason F.; Rettie, Alexander J. E.; Robredo, Iñigo Journal of the American Chemical Society, Vol. 142, Issue 13 https://doi.org/10.1021/jacs.0c00809	journal	March 2020
New Compounds and Phase Selection of Nickel Sulfides via Oxidation State Control in Molten Hydroxides Zhou, Xiuquan; Mandia, David J.; Park, Hyowon Journal of the American Chemical Society, Vol. 143, Issue 34 https://doi.org/10.1021/jacs.1c05107	journal	August 2021
The Two-Dimensional A _x Cd _x Bi _{4– x} Q ₆ (A = K, Rb, Cs; Q = S, Se): Direct Bandgap Semiconductors and Ion-Exchange Materials Zhao, Jing; Islam, Saiful M.; Kontsevoi, Oleg Y. Journal of the American Chemical Society, Vol. 139, Issue 20 https://doi.org/10.1021/jacs.7b02243	journal	May 2017
Homologous Series of 2D Chalcogenides Cs–Ag–Bi–Q (Q = S, Se) with Ion-Exchange Properties Zhao, Jing; Islam, Saiful M.; Hao, Shiqiang Journal of the American Chemical Society, Vol. 139, Issue 36 https://doi.org/10.1021/jacs.7b06373	journal	August 2017
Unique [Mn ₆ Bi ₅ ] ⁻ Nanowires in KMn ₆ Bi ₅ : A Quasi-One-Dimensional Antiferromagnetic Metal Bao, Jin-Ke; Tang, Zhang-Tu; Jung, Hee Joon Journal of the American Chemical Society, Vol. 140, Issue 12 https://doi.org/10.1021/jacs.8b00465	journal	February 2018
A New Three-Dimensional Subsulfide Ir ₂ In ₈ S with Dirac Semimetal Behavior Khoury, Jason F.; Rettie, Alexander J. E.; Khan, Mojammel A. Journal of the American Chemical Society, Vol. 141, Issue 48 https://doi.org/10.1021/jacs.9b10147	journal	November 2019
Crystal Orbital Hamilton Population (COHP) Analysis As Projected from Plane-Wave Basis Sets Deringer, Volker L.; Tchougréeff, Andrei L.; Dronskowski, Richard The Journal of Physical Chemistry A, Vol. 115, Issue 21 https://doi.org/10.1021/jp202489s	journal	June 2011
Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals Zhao, Li-Dong; Lo, Shih-Han; Zhang, Yongsheng Nature, Vol. 508, Issue 7496, p. 373-377 https://doi.org/10.1038/nature13184	journal	April 2014
Large, non-saturating magnetoresistance in WTe2 Ali, Mazhar N.; Xiong, Jun; Flynn, Steven Nature, Vol. 514, Issue 7521 https://doi.org/10.1038/nature13763	journal	September 2014
Type-II Weyl semimetals Soluyanov, Alexey A.; Gresch, Dominik; Wang, Zhijun Nature, Vol. 527, Issue 7579 https://doi.org/10.1038/nature15768	journal	November 2015
Giant anomalous Hall effect in a ferromagnetic kagome-lattice semimetal Liu, Enke; Sun, Yan; Kumar, Nitesh Nature Physics, Vol. 14, Issue 11 https://doi.org/10.1038/s41567-018-0234-5	journal	July 2018
Negative flat band magnetism in a spin–orbit-coupled correlated kagome magnet Yin, Jia-Xin; Zhang, Songtian S.; Chang, Guoqing Nature Physics, Vol. 15, Issue 5 https://doi.org/10.1038/s41567-019-0426-7	journal	February 2019
Comprehensive search for topological materials using symmetry indicators Tang, Feng; Po, Hoi Chun; Vishwanath, Ashvin Nature, Vol. 566, Issue 7745 https://doi.org/10.1038/s41586-019-0937-5	journal	February 2019
Charge-density-wave-driven electronic nematicity in a kagome superconductor Nie, Linpeng; Sun, Kuanglv; Ma, Wanru Nature, Vol. 604, Issue 7904 https://doi.org/10.1038/s41586-022-04493-8	journal	February 2022
Discovery of chalcogenides structures and compositions using mixed fluxes Zhou, Xiuquan; Kolluru, Venkata Surya Chaitanya; Xu, Wenqian Nature, Vol. 612, Issue 7938 https://doi.org/10.1038/s41586-022-05307-7	journal	November 2022
Coherent approach to two-dimensional heterolayered oxychalcogenides using molten hydroxides Zhou, Xiuquan; Malliakas, Christos D.; Yakovenko, Andrey A. Nature Synthesis, Vol. 1, Issue 9 https://doi.org/10.1038/s44160-022-00130-4	journal	August 2022
Direct synthesis of metastable phases of 2D transition metal dichalcogenides Sokolikova, Maria S.; Mattevi, Cecilia Chemical Society Reviews, Vol. 49, Issue 12 https://doi.org/10.1039/d0cs00143k	journal	January 2020
The contribution to the electrical resistance of metals from collisions between electrons Baber, W. G. Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences, Vol. 158, Issue 894, p. 383-396 https://doi.org/10.1098/rspa.1937.0027	journal	January 1937
Three-dimensional Dirac semimetals: Design principles and predictions of new materials Gibson, Q. D.; Schoop, L. M.; Muechler, L. Physical Review B, Vol. 91, Issue 20 https://doi.org/10.1103/physrevb.91.205128	journal	May 2015
Observation of Dirac-like energy band and unusual spectral line shape in quasi-one-dimensional superconductor Tl 2 Mo 6 Se 6 Nakayama, Kosuke; Wang, Zhiwei; Trang, Chi Xuan Physical Review B, Vol. 98, Issue 14 https://doi.org/10.1103/physrevb.98.140502	journal	October 2018
Local Disorder-Induced Elevation of Intrinsic Anomalous Hall Conductance in an Electron-Doped Magnetic Weyl Semimetal Shen, Jianlei; Yao, Qiushi; Zeng, Qingqi Physical Review Letters, Vol. 125, Issue 8 https://doi.org/10.1103/physrevlett.125.086602	journal	August 2020
Cs V 3 Sb 5 : A Z 2 Topological Kagome Metal with a Superconducting Ground State Ortiz, Brenden R.; Teicher, Samuel M. L.; Hu, Yong Physical Review Letters, Vol. 125, Issue 24 https://doi.org/10.1103/physrevlett.125.247002	journal	December 2020
Pressure-Induced Superconductivity up to 9 K in the Quasi-One-Dimensional KMn6Bi5 Liu, Z. Y.; Dong, Q. X.; Yang, P. T. Physical Review Letters, Vol. 128, Issue 18 https://doi.org/10.1103/physrevlett.128.187001	journal	May 2022
Superconductivity in Quasi-One-Dimensional K 2 Cr 3 As 3 with Significant Electron Correlations Bao, Jin-Ke; Liu, Ji-Yong; Ma, Cong-Wei Physical Review X, Vol. 5, Issue 1 https://doi.org/10.1103/physrevx.5.011013	journal	February 2015
The crystal structures of Nb ₃ Se ₄ and Nb ₃ Te ₄ Selte, K.; Kjekshus, A. Acta Crystallographica, Vol. 17, Issue 12 https://doi.org/10.1107/s0365110x64003875	journal	December 1964
The crystal structures of NbT ₂ and TaTe ₂ Brown, B. E. Acta Crystallographica, Vol. 20, Issue 2 https://doi.org/10.1107/s0365110x66000501	journal	February 1966
Surface states in bulk single crystal of topological semimetal Co ₃ Sn ₂ S ₂ toward water oxidation Li, Guowei; Xu, Qiunan; Shi, Wujun Science Advances, Vol. 5, Issue 8 https://doi.org/10.1126/sciadv.aaw9867	journal	August 2019
Magnetic Weyl semimetal phase in a Kagomé crystal Liu, D. F.; Liang, A. J.; Liu, E. K. Science, Vol. 365, Issue 6459 https://doi.org/10.1126/science.aav2873	journal	September 2019
Synthesis and Structure of Li ₄ GeS ₄ ^a Matsushita, Yoshitaka; Kanatzidis, Mercouri G. Zeitschrift für Naturforschung B, Vol. 53, Issue 1 https://doi.org/10.1515/znb-1998-0107	journal	January 1998
The Crystal Structures of Nb5Se4 and Nb5Te4. Selte, Kari; Kjekshus, Arne; Ewing, V. Acta Chemica Scandinavica, Vol. 17 https://doi.org/10.3891/acta.chem.scand.17-2560	journal	January 1963
On the Crystal Structure of NbTe4. Selte, Kari; Kjekshus, Arne; Petersen, Cherry Schiander Acta Chemica Scandinavica, Vol. 18 https://doi.org/10.3891/acta.chem.scand.18-0690	journal	January 1964
Efficient Rotation of Local Basis Functions Using Real Spherical Harmonics Maintz, S.; Esser, M.; Dronskowski, R. Acta Physica Polonica B, Vol. 47, Issue 4 https://doi.org/10.5506/aphyspolb.47.1165	journal	January 2016

Similar Records

Synthesis, characterization, and electrical conductivity of CsCu{sub 2}MTe{sub 4} (M = Nb, Ta)

Conference · Sat Dec 30 23:00:00 EST 1995 · OSTI ID:214961

A new one-dimensional quaternary metal thiophosphate: Synthesis and structure of KNb{sub 2}PS{sub 10}

Journal Article · Wed Jun 19 00:00:00 EDT 1996 · Inorganic Chemistry · OSTI ID:274265

Syntheses, structures, and characterization of the two-dimensional tellurides CsCu{sub 2}MTe{sub 4}(M = Nb, Ta)

Journal Article · Thu Jan 04 23:00:00 EST 1996 · Journal of Solid State Chemistry · OSTI ID:223719

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
anions
crystal structure
crystals
fluxes
transition metals

CSD 2235758: Experimental Crystal Structure Determination Fan, Sun,; Haoyu, Yue,; Danilo, Puggioni, https://doi.org/10.25505/fiz.icsd.cc2f1h77 The current record is supplemented by this dataset	dataset	January 2023
CSD 2235759: Experimental Crystal Structure Determination Fan, Sun,; Haoyu, Yue,; Danilo, Puggioni, https://doi.org/10.25505/fiz.icsd.cc2f1h88 The current record is supplemented by this dataset	dataset	January 2023
CSD 2235767: Experimental Crystal Structure Determination Fan, Sun,; Haoyu, Yue,; Danilo, Puggioni, https://doi.org/10.25505/fiz.icsd.cc2f1hjj The current record is supplemented by this dataset	dataset	January 2023
CSD 2239730: Experimental Crystal Structure Determination Fan, Sun,; Haoyu, Yue,; Danilo, Puggioni, https://doi.org/10.25505/fiz.icsd.cc2f5mcm The current record is supplemented by this dataset	dataset	January 2023

Phase Discovery and Selected Synthesis of Subvalent Niobium Tellurides Using a Polytelluride Flux Strategy

Citation Formats

References (71)

Linked Research (4)

Similar Records

Related Subjects