A new one-dimensional quaternary metal thiophosphate: Synthesis and structure of KNb{sub 2}PS{sub 10}
- Ajou Univ., Suwon (Korea, Republic of)
The new one-dimensional quaternary metal thiophosphate KNb{sub 2}PS{sub 10} has been synthesized by using a eutectic mixture of KVCl/LiCl and structurally characterized. The structure of KNb{sub 2}PS{sub 10} is closely related to that of Nb{sub 2}PS{sub 10} and comprises infinite one-dimensional chains composed by NbS{sub 8} and PS{sub 4} polyhedra. These chains are separated from one another by K{sup +} cations. A chain may be formulated as {sub {infinity}}{sup 1}[Nb{sup 4+}{sub 2}P{sup 5+}(S{sub 2}){sup 2{minus}}{sub 3}(S{sup 2{minus}}){sub 4}{sup {minus}}].
- OSTI ID:
- 274265
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 13 Vol. 35; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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