Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

Daliran, Saba; Oveisi, Ali Reza; Kung, Chung-Wei; Sen, Unal; Dhakshinamoorthy, Amarajothi; Chuang, Cheng-Hsun; Khajeh, Mostafa; Erkartal, Mustafa; Hupp, Joseph T.

doi:10.1039/D3CS01057K

Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

Journal Article · Mon Jan 01 00:00:00 EST 2024 · Chemical Society Reviews

DOI:https://doi.org/10.1039/D3CS01057K· OSTI ID:2350704

^[1]; ^[2]; ^[3]; ^[4]; ^[5]; Chuang, Cheng-Hsun ^[3]; ^[2]; ^[6]; ^[7]

Department of Organic Chemistry, Faculty of Chemistry, Lorestan University, Khorramabad 68151-44316, Iran
Department of Chemistry, University of Zabol, P.O. Box: 98615-538, Zabol, Iran
Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan City 70101, Taiwan
Department of Materials Science and Engineering, Faculty of Engineering, Eskisehir Technical University, Eskisehir 26555, Turkey
Departamento de Quimica, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 Valencia, Spain, School of Chemistry, Madurai Kamaraj University, Madurai 625021, India
Department of Basic Sciences, Faculty of Engineering, Architecture and Design, Bartin University, Bartin 74110, Turkey
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA

This review highlights the promising prospects of defective zirconium-based MOFs in addressing challenging energy- and environment-related problems, positioning them as versatile tools toward a cleaner and more sustainable future.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: FG02-87ER13808

OSTI ID:: 2350704

Alternate ID(s):: OSTI ID: 2578214

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews; ISSN 0306-0012; ISSN CSRVBR

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Tailoring Defect Density in UiO-66 Frameworks for Enhanced Pb(II) Adsorption Ali, Shafqat; Zuhra, Zareen; Abbas, Yasir Langmuir, Vol. 37, Issue 46 https://doi.org/10.1021/acs.langmuir.1c02032	journal	November 2021
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Tuning the Wettability of Metal–Organic Frameworks via Defect Engineering for Efficient Oil/Water Separation Huang, Yi; Jiao, Yang; Chen, Ting ACS Applied Materials & Interfaces, Vol. 12, Issue 30 https://doi.org/10.1021/acsami.0c08803	journal	June 2020
Quest for an Efficient 2-in-1 MOF-Based Catalytic System for Cycloaddition of CO₂ to Epoxides under Mild Conditions Pander, Marzena; Janeta, Mateusz; Bury, Wojciech ACS Applied Materials & Interfaces, Vol. 13, Issue 7 https://doi.org/10.1021/acsami.0c20437	journal	February 2021
Zirconium Metal–Organic Frameworks Integrating Chloride Ions for Ammonia Capture and/or Chemical Separation Liu, Jian; Chen, Zhijie; Wang, Rui ACS Applied Materials & Interfaces, Vol. 13, Issue 19 https://doi.org/10.1021/acsami.1c03717	journal	May 2021
Product Inhibition and the Catalytic Destruction of a Nerve Agent Simulant by Zirconium-Based Metal–Organic Frameworks Liao, Yijun; Sheridan, Thomas; Liu, Jian ACS Applied Materials & Interfaces, Vol. 13, Issue 26 https://doi.org/10.1021/acsami.1c05062	journal	June 2021
Generating Catalytic Sites in UiO-66 through Defect Engineering Feng, Xiao; Jena, Himanshu Sekhar; Krishnaraj, Chidharth ACS Applied Materials & Interfaces, Vol. 13, Issue 51 https://doi.org/10.1021/acsami.1c13525	journal	December 2021
Zirconium-Based Metal–Organic Framework Mixed-Matrix Membranes as Analytical Devices for the Trace Analysis of Complex Cosmetic Samples in the Assessment of Their Personal Care Product Content Gutiérrez-Serpa, Adrián; Kundu, Tanay; Pasán, Jorge ACS Applied Materials & Interfaces, Vol. 14, Issue 3 https://doi.org/10.1021/acsami.1c21284	journal	January 2022
Effect of the Defect Modulator and Ligand Length of Metal–Organic Frameworks on Carbon Dioxide Photoreduction Wang, Shi-Qing; Wang, Xinzhu; Zhang, Xiao-Yu ACS Applied Materials & Interfaces, Vol. 13, Issue 51 https://doi.org/10.1021/acsami.1c21663	journal	December 2021
CsCu₂I₃ Nanoparticles Incorporated within a Mesoporous Metal–Organic Porphyrin Framework as a Catalyst for One-Pot Click Cycloaddition and Oxidation/Knoevenagel Tandem Reaction Daliran, Saba; Khajeh, Mostafa; Oveisi, Ali Reza ACS Applied Materials & Interfaces, Vol. 14, Issue 32 https://doi.org/10.1021/acsami.2c04364	journal	August 2022
Visible-Light-Responsive UiO-66(Zr) with Defects Efficiently Promoting Photocatalytic CO₂ Reduction He, Yiqiang; Li, Chunguang; Chen, Xiao-Bo ACS Applied Materials & Interfaces, Vol. 14, Issue 25 https://doi.org/10.1021/acsami.2c06993	journal	June 2022
Computational Characterization of Zr-Oxide MOFs for Adsorption Applications Oktavian, Rama; Schireman, Raymond; Glasby, Lawson T. ACS Applied Materials & Interfaces, Vol. 14, Issue 51 https://doi.org/10.1021/acsami.2c13391	journal	December 2022
Synergy of Paired Brønsted–Lewis Acid Sites on Defects of Zr-MIL-140A for Methanol Dehydration Xiao, Yue; Zhang, Minxin; Yang, Dong ACS Applied Materials & Interfaces, Vol. 15, Issue 29 https://doi.org/10.1021/acsami.3c02939	journal	July 2023
Effect of a Zr-Based Metal–Organic Framework Structure on the Properties of Its Composite with Polyaniline Milakin, Konstantin A.; Gupta, Sonal; Kobera, Libor ACS Applied Materials & Interfaces, Vol. 15, Issue 19 https://doi.org/10.1021/acsami.3c03870	journal	May 2023
Effect of Missing-Linker Defects and Ion Exchange on Stability and Proton Conduction of a Sulfonated Layered Zr-MOF Szufla, Monika; Navarro, Jorge A. R.; Góra-Marek, Kinga ACS Applied Materials & Interfaces, Vol. 15, Issue 23 https://doi.org/10.1021/acsami.3c03873	journal	June 2023
MOF-Fabric Composites Based on a Multi-Functional MOF as Luminescent Sensors for a Neurotransmitter and an Anti-Cancer Drug Ghosh, Subhrajyoti; Krishnan, Jayaraman; Hossain, Sk Sakir ACS Applied Materials & Interfaces, Vol. 15, Issue 22 https://doi.org/10.1021/acsami.3c04278	journal	May 2023
Engendering Long-Term Air and Light Stability of a TiO ₂ -Supported Porphyrinic Dye via Atomic Layer Deposition Hoffeditz, William L.; Son, Ho-Jin; Pellin, Michael J. ACS Applied Materials & Interfaces, Vol. 8, Issue 50 https://doi.org/10.1021/acsami.6b10844	journal	December 2016
Stable Zr(IV)-Based Metal–Organic Frameworks with Predesigned Functionalized Ligands for Highly Selective Detection of Fe(III) Ions in Water Wang, Bin; Yang, Qi; Guo, Chao ACS Applied Materials & Interfaces, Vol. 9, Issue 11 https://doi.org/10.1021/acsami.7b00918	journal	March 2017
Size Modulation of Zirconium-Based Metal Organic Frameworks for Highly Efficient Phosphate Remediation Gu, Yue; Xie, Donghua; Ma, Yue ACS Applied Materials & Interfaces, Vol. 9, Issue 37 https://doi.org/10.1021/acsami.7b10024	journal	September 2017
Boronic Acid Moiety as Functional Defect in UiO-66 and Its Effect on Hydrogen Uptake Capacity and Selective CO₂ Adsorption: A Comparative Study Erkartal, Mustafa; Sen, Unal ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b16937	journal	December 2017
Zr(IV)-Based Metal-Organic Framework with T-Shaped Ligand: Unique Structure, High Stability, Selective Detection, and Rapid Adsorption of Cr ₂ O ₇ ^2– in Water He, Tao; Zhang, Yong-Zheng; Kong, Xiang-Jing ACS Applied Materials & Interfaces, Vol. 10, Issue 19 https://doi.org/10.1021/acsami.8b03987	journal	May 2018
Highly Effective Removal of Nonsteroidal Anti-inflammatory Pharmaceuticals from Water by Zr(IV)-Based Metal–Organic Framework: Adsorption Performance and Mechanisms Lin, Shuo; Zhao, Yufeng; Yun, Yeoung-Sang ACS Applied Materials & Interfaces, Vol. 10, Issue 33 https://doi.org/10.1021/acsami.8b08596	journal	August 2018
Lithiated Defect Sites in Zr Metal–Organic Framework for Enhanced Sulfur Utilization in Li–S Batteries Baumann, Avery E.; Burns, David A.; Díaz, José C. ACS Applied Materials & Interfaces, Vol. 11, Issue 2 https://doi.org/10.1021/acsami.8b19034	journal	December 2018
Exploiting π–π Interactions to Design an Efficient Sorbent for Atrazine Removal from Water Akpinar, Isil; Drout, Riki J.; Islamoglu, Timur ACS Applied Materials & Interfaces, Vol. 11, Issue 6 https://doi.org/10.1021/acsami.8b20355	journal	February 2019
Metal–Organic Framework Crystal-Assembled Optical Sensors for Chemical Vapors: Effects of Crystal Sizes and Missing-Linker Defects on Sensing Performances Zhang, Rui; Zhang, Danrui; Yao, Youjin ACS Applied Materials & Interfaces, Vol. 11, Issue 23 https://doi.org/10.1021/acsami.9b05933	journal	May 2019
Defectous UiO-66 MOF Nanocomposites as Reactive Media of Superior Protection against Toxic Vapors Giannakoudakis, Dimitrios A.; Bandosz, Teresa J. ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b17314	journal	November 2019
Defect Control in Zr-Based Metal–Organic Framework Nanoparticles for Arsenic Removal from Water Assaad, Nisrine; Sabeh, Ghewa; Hmadeh, Mohamad ACS Applied Nano Materials, Vol. 3, Issue 9 https://doi.org/10.1021/acsanm.0c01696	journal	August 2020
Pore-Confined Silver Nanoparticles in a Porphyrinic Metal–Organic Framework for Electrochemical Nitrite Detection Wang, Yi-Ching; Chen, Yu-Chuan; Chuang, Wen-Shuo ACS Applied Nano Materials, Vol. 3, Issue 9 https://doi.org/10.1021/acsanm.0c02052	journal	August 2020
Defective Metal–Organic Framework Nanocrystals as Signal Amplifiers for Electrochemical Dopamine Sensing Chang, Yu-Na; Shen, Cheng-Hui; Huang, Chi-Wei ACS Applied Nano Materials, Vol. 6, Issue 5 https://doi.org/10.1021/acsanm.2c05402	journal	February 2023
Defect-Tailoring and Titanium Substitution in Metal–Organic Framework UiO-66-NH₂ for the Photocatalytic Degradation of Cr(VI) to Cr(III) Feng, Yi; Chen, Qian; Cao, Mengjue ACS Applied Nano Materials, Vol. 2, Issue 9 https://doi.org/10.1021/acsanm.9b01403	journal	August 2019
In Situ Construction of Metal–Organic Frameworks as Smart Channels for the Effective Electrocatalytic Reduction of Nitrate at Ultralow Concentrations to Ammonia Wang, Zhichao; Liu, Sisi; Wang, Mengfan ACS Catalysis, Vol. 13, Issue 13 https://doi.org/10.1021/acscatal.3c01821	journal	June 2023
2-Propanol Dehydration on the Nodes of the Metal–Organic Framework UiO-66: Distinguishing Catalytic Sites for Formation of Propene and Di-isopropyl Ether Das, Sonali; Yang, Dong; Conley, Edward T. ACS Catalysis, Vol. 13, Issue 21 https://doi.org/10.1021/acscatal.3c03500	journal	October 2023
Probing the Mechanism of Hydrolytic Degradation of Nerve Agent Simulant with Zirconium-Based Metal–Organic Frameworks Liao, Yijun; Sheridan, Thomas R.; Liu, Jian ACS Catalysis, Vol. 14, Issue 1 https://doi.org/10.1021/acscatal.3c04469	journal	December 2023
One Step Backward Is Two Steps Forward: Enhancing the Hydrolysis Rate of UiO-66 by Decreasing [OH ^– ] Katz, Michael J.; Klet, Rachel C.; Moon, Su-Young ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b00785	journal	July 2015
Recent Trends and Perspectives in Electrochemical Water Splitting with an Emphasis on Sulfide, Selenide, and Phosphide Catalysts of Fe, Co, and Ni: A Review Anantharaj, Sengeni; Ede, Sivasankara Rao; Sakthikumar, Kuppan ACS Catalysis, Vol. 6, Issue 12 https://doi.org/10.1021/acscatal.6b02479	journal	November 2016
Tuning Zr ₁₂ O ₂₂ Node Defects as Catalytic Sites in the Metal–Organic Framework hcp UiO-66 Chen, Xi; Lyu, Yinghui; Wang, Zhengyan ACS Catalysis, Vol. 10, Issue 5 https://doi.org/10.1021/acscatal.9b04905	journal	January 2020
Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues Brozek, Carl K.; Michaelis, Vladimir K.; Ong, Ta-Chung ACS Central Science, Vol. 1, Issue 5 https://doi.org/10.1021/acscentsci.5b00247	journal	July 2015
Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends Yuan, Shuai; Qin, Jun-Sheng; Lollar, Christina T. ACS Central Science, Vol. 4, Issue 4 https://doi.org/10.1021/acscentsci.8b00073	journal	February 2018
Sulfonate-Grafted Metal–Organic Framework─A Porous Alternative to Nafion for Electrochemical Sensors Shen, Cheng-Hui; Chang, Yu-Na; Chen, You-Liang ACS Materials Letters, Vol. 5, Issue 7 https://doi.org/10.1021/acsmaterialslett.3c00389	journal	June 2023
Probing Structural Imperfections: Protein-Aided Defect Characterization in Metal–Organic Frameworks Sha, Fanrui; Xie, Haomiao; Kirlikovali, Kent O. ACS Materials Letters, Vol. 6, Issue 4 https://doi.org/10.1021/acsmaterialslett.4c00199	journal	March 2024
Dual-Function Metal–Organic Framework as a Versatile Catalyst for Detoxifying Chemical Warfare Agent Simulants Liu, Yangyang; Moon, Su-Young; Hupp, Joseph T. ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b05660	journal	October 2015
Nanosizing a Metal–Organic Framework Enzyme Carrier for Accelerating Nerve Agent Hydrolysis Li, Peng; Moon, Su-Young; Guelta, Mark A. ACS Nano, Vol. 10, Issue 10 https://doi.org/10.1021/acsnano.6b04996	journal	October 2016
Back to the Basics: Developing Advanced Metal–Organic Frameworks Using Fundamental Chemistry Concepts Kirlikovali, Kent O.; Hanna, Sylvia L.; Son, Florencia A. ACS Nanoscience Au, Vol. 3, Issue 1 https://doi.org/10.1021/acsnanoscienceau.2c00046	journal	December 2022
Water-Stable Nanoscale Zirconium-Based Metal–Organic Frameworks for the Effective Removal of Glyphosate from Aqueous Media Pankajakshan, Asha; Sinha, Mekhola; Ojha, Anupam Anand ACS Omega, Vol. 3, Issue 7 https://doi.org/10.1021/acsomega.8b00921	journal	July 2018
Two-Dimensional Zirconium-Based Metal–Organic Framework Nanosheet Composites Embedded with Au Nanoclusters: A Highly Sensitive Electrochemical Aptasensor toward Detecting Cocaine Su, Fangfang; Zhang, Shuai; Ji, Hongfei ACS Sensors, Vol. 2, Issue 7 https://doi.org/10.1021/acssensors.7b00268	journal	June 2017
Effective Recovery of Pt(IV) from Acidic Solution by a Defective Metal–Organic Frameworks Using Central Composite Design for Synthesis Lin, Shuo; Bediako, John Kwame; Song, Myung-Hee ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 8 https://doi.org/10.1021/acssuschemeng.8b04637	journal	March 2019
Highly Defective UiO-66 Materials for the Adsorptive Removal of Perfluorooctanesulfonate Clark, Chelsea A.; Heck, Kimberly N.; Powell, Camilah D. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 7 https://doi.org/10.1021/acssuschemeng.8b05572	journal	March 2019
Effective Adsorption and Enhanced Removal of Organophosphorus Pesticides from Aqueous Solution by Zr-Based MOFs of UiO-67 Zhu, Xiangyang; Li, Bing; Yang, Jian ACS Applied Materials & Interfaces, Vol. 7, Issue 1 https://doi.org/10.1021/am5059074	journal	December 2014
Detailed Structure Analysis of Atomic Positions and Defects in Zirconium Metal–Organic Frameworks Øien, Sigurd; Wragg, David; Reinsch, Helge Crystal Growth & Design, Vol. 14, Issue 11 https://doi.org/10.1021/cg501386j	journal	October 2014
Synthesis and Stability of Tagged UiO-66 Zr-MOFs Kandiah, Mathivathani; Nilsen, Merete Hellner; Usseglio, Sandro Chemistry of Materials, Vol. 22, Issue 24 https://doi.org/10.1021/cm102601v	journal	December 2010
Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66 Shearer, Greig C.; Chavan, Sachin; Ethiraj, Jayashree Chemistry of Materials, Vol. 26, Issue 14 https://doi.org/10.1021/cm501859p	journal	July 2014
Topotactic Transformations of Metal–Organic Frameworks to Highly Porous and Stable Inorganic Sorbents for Efficient Radionuclide Sequestration Abney, Carter W.; Taylor-Pashow, Kathryn M. L.; Russell, Shane R. Chemistry of Materials, Vol. 26, Issue 18 https://doi.org/10.1021/cm501894h	journal	September 2014
Conventional and Unconventional Metal–Organic Frameworks Based on Phosphonate Ligands: MOFs and UMOFs Gagnon, Kevin J.; Perry, Houston P.; Clearfield, Abraham Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr2002257	journal	September 2011
Water Stability and Adsorption in Metal–Organic Frameworks Burtch, Nicholas C.; Jasuja, Himanshu; Walton, Krista S. Chemical Reviews, Vol. 114, Issue 20, p. 10575-10612 https://doi.org/10.1021/cr5002589	journal	September 2014
A Highly Stable Rhenium−Cobalt System for Photocatalytic H ₂ Production: Unraveling the Performance-Limiting Steps Probst, Benjamin; Rodenberg, Alexander; Guttentag, Miguel Inorganic Chemistry, Vol. 49, Issue 14 https://doi.org/10.1021/ic100036v	journal	July 2010
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks Morris, William; Volosskiy, Boris; Demir, Selcuk Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445 https://doi.org/10.1021/ic300825s	journal	June 2012
In Situ Energy-Dispersive X-ray Diffraction for the Synthesis Optimization and Scale-up of the Porous Zirconium Terephthalate UiO-66 Ragon, Florence; Horcajada, Patricia; Chevreau, Hubert Inorganic Chemistry, Vol. 53, Issue 5 https://doi.org/10.1021/ic402514n	journal	February 2014
MOF Functionalization via Solvent-Assisted Ligand Incorporation: Phosphonates vs Carboxylates Deria, Pravas; Bury, Wojciech; Hod, Idan Inorganic Chemistry, Vol. 54, Issue 5 https://doi.org/10.1021/ic502639v	journal	February 2015
Photocatalytic Generation of Hydrogen from Water Using a Platinum(II) Terpyridyl Acetylide Chromophore Du, Pingwu; Schneider, Jacob; Jarosz, Paul Journal of the American Chemical Society, Vol. 128, Issue 24 https://doi.org/10.1021/ja0610683	journal	June 2006
Glass-Encapsulated Light Harvesters: More Efficient Dye-Sensitized Solar Cells by Deposition of Self-Aligned, Conformal, and Self-Limited Silica Layers Son, Ho-Jin; Wang, Xinwei; Prasittichai, Chaiya Journal of the American Chemical Society, Vol. 134, Issue 23 https://doi.org/10.1021/ja300015n	journal	May 2012
Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr) Vermoortele, Frederik; Bueken, Bart; Le Bars, Gaëlle Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja405078u	journal	July 2013
Dye Stabilization and Enhanced Photoelectrode Wettability in Water-Based Dye-Sensitized Solar Cells through Post-assembly Atomic Layer Deposition of TiO ₂ Son, Ho-Jin; Prasittichai, Chaiya; Mondloch, Joseph E. Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja406538a	journal	July 2013
An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence Jiang, Hai-Long; Feng, Dawei; Wang, Kecheng Journal of the American Chemical Society, Vol. 135, Issue 37 https://doi.org/10.1021/ja406844r	journal	September 2013
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381 https://doi.org/10.1021/ja500330a	journal	March 2014
Structural Complexity in Metal–Organic Frameworks: Simultaneous Modification of Open Metal Sites and Hierarchical Porosity by Systematic Doping with Defective Linkers Fang, Zhenlan; Dürholt, Johannes P.; Kauer, Max Journal of the American Chemical Society, Vol. 136, Issue 27 https://doi.org/10.1021/ja503218j	journal	June 2014
Direct Imaging of Correlated Defect Nanodomains in a Metal–Organic Framework Johnstone, Duncan N.; Firth, Francesca C. N.; Grey, Clare P. Journal of the American Chemical Society, Vol. 142, Issue 30 https://doi.org/10.1021/jacs.0c04468	journal	July 2020
A Porphyrinic Zirconium Metal–Organic Framework for Oxygen Reduction Reaction: Tailoring the Spacing between Active-Sites through Chain-Based Inorganic Building Units Cichocka, Magdalena Ola; Liang, Zuozhong; Feng, Dawei Journal of the American Chemical Society, Vol. 142, Issue 36 https://doi.org/10.1021/jacs.0c06329	journal	August 2020
Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- and Dodecanuclear Clusters as Well as a Small Organic Linker Molecule Leubner, Sebastian; Bengtsson, Viktor E. G.; Synnatschke, Kevin Journal of the American Chemical Society, Vol. 142, Issue 37 https://doi.org/10.1021/jacs.0c06978	journal	August 2020
Node-Accessible Zirconium MOFs Lu, Zhiyong; Liu, Jian; Zhang, Xuan Journal of the American Chemical Society, Vol. 142, Issue 50 https://doi.org/10.1021/jacs.0c09782	journal	December 2020
Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study Alsadun, Norah; Mouchaham, Georges; Guillerm, Vincent Journal of the American Chemical Society, Vol. 142, Issue 49 https://doi.org/10.1021/jacs.0c10007	journal	November 2020
Unexpected “Spontaneous” Evolution of Catalytic, MOF-Supported Single Cu(II) Cations to Catalytic, MOF-Supported Cu(0) Nanoparticles Yang, Ying; Zhang, Xuan; Kanchanakungwankul, Siriluk Journal of the American Chemical Society, Vol. 142, Issue 50 https://doi.org/10.1021/jacs.0c10367	journal	December 2020
Structural Diversity of Zirconium Metal–Organic Frameworks and Effect on Adsorption of Toxic Chemicals Chen, Yongwei; Zhang, Xuan; Mian, Mohammad Rasel Journal of the American Chemical Society, Vol. 142, Issue 51 https://doi.org/10.1021/jacs.0c10400	journal	December 2020
Neighboring Zn–Zr Sites in a Metal–Organic Framework for CO ₂ Hydrogenation Zhang, Jingzheng; An, Bing; Li, Zhe Journal of the American Chemical Society, Vol. 143, Issue 23 https://doi.org/10.1021/jacs.1c03283	journal	June 2021
Creation of Exclusive Artificial Cluster Defects by Selective Metal Removal in the (Zn, Zr) Mixed-Metal UiO-66 Feng, Xiao; Jena, Himanshu Sekhar; Krishnaraj, Chidharth Journal of the American Chemical Society, Vol. 143, Issue 51 https://doi.org/10.1021/jacs.1c05357	journal	December 2021
Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal–Organic Framework Castner, Ashleigh T.; Su, Hao; Svensson Grape, Erik Journal of the American Chemical Society, Vol. 144, Issue 13 https://doi.org/10.1021/jacs.1c13377	journal	March 2022
Tröger’s Base Chemistry in Solution and in Zr(IV)-Based Metal–Organic Frameworks Gong, Wei; Kazem-Rostami, Masoud; Son, Florencia A. Journal of the American Chemical Society, Vol. 144, Issue 49 https://doi.org/10.1021/jacs.2c08623	journal	December 2022
Node Distortion as a Tunable Mechanism for Negative Thermal Expansion in Metal–Organic Frameworks Chen, Zhihengyu; Stroscio, Gautam D.; Liu, Jian Journal of the American Chemical Society, Vol. 145, Issue 1 https://doi.org/10.1021/jacs.2c09877	journal	December 2022
Influence of 1-Butene Adsorption on the Dimerization Activity of Single Metal Cations on UiO-66 Nodes Löbbert, Laura; Chheda, Saumil; Zheng, Jian Journal of the American Chemical Society, Vol. 145, Issue 2 https://doi.org/10.1021/jacs.2c12192	journal	January 2023
Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation Gong, Wei; Xie, Yi; Wang, Xingjie Journal of the American Chemical Society, Vol. 145, Issue 4 https://doi.org/10.1021/jacs.2c13171	journal	January 2023
Unlocking New Topologies in Zr-Based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder Koschnick, Charlotte; Terban, Maxwell W.; Frison, Ruggero Journal of the American Chemical Society, Vol. 145, Issue 18 https://doi.org/10.1021/jacs.2c13731	journal	April 2023
Unveiling Unexpected Modulator-CO₂ Dynamics within a Zirconium Metal–Organic Framework Rayder, Thomas M.; Formalik, Filip; Vornholt, Simon M. Journal of the American Chemical Society, Vol. 145, Issue 20 https://doi.org/10.1021/jacs.3c01146	journal	May 2023
Reticular Chemistry in Its Chiral Form: Axially Chiral Zr(IV)-Spiro Metal–Organic Framework as a Case Study Gong, Wei; Chen, Xinfa; Fahy, Kira M. Journal of the American Chemical Society, Vol. 145, Issue 25 https://doi.org/10.1021/jacs.3c03036	journal	June 2023
Water-Accelerated Transport: Vapor-Phase Nerve Agent Simulant Delivery within a Catalytic Zirconium Metal–Organic Framework as a Function of Relative Humidity Wang, Rui; Shi, Kaihang; Liu, Jian Journal of the American Chemical Society https://doi.org/10.1021/jacs.3c03708	journal	June 2023
Yolk–Shell and Hollow Zr/Ce-UiO-66 for Manipulating Selectivity in Tandem Reactions and Photoreactions He, Hui-Hui; Yuan, Jiang-Pei; Cai, Pei-Yu Journal of the American Chemical Society, Vol. 145, Issue 31 https://doi.org/10.1021/jacs.3c03883	journal	July 2023
Postsynthetic Modification of the Nonanuclear Node in a Zirconium Metal–Organic Framework for Photocatalytic Oxidation of Hydrocarbons Khoo, Rebecca Shu Hui; Fiankor, Christian; Yang, Sizhuo Journal of the American Chemical Society, Vol. 145, Issue 44 https://doi.org/10.1021/jacs.3c07237	journal	October 2023
A Nanocavitation Approach to Understanding Water Capture, Water Release, and Framework Physical Stability in Hierarchically Porous MOFs Liu, Jian; Prelesnik, Jesse L.; Patel, Roshan Journal of the American Chemical Society, Vol. 145, Issue 51 https://doi.org/10.1021/jacs.3c07624	journal	December 2023
A Fluorinated BODIPY-Based Zirconium Metal–Organic Framework for In Vivo Enhanced Photodynamic Therapy Chen, Xu; Mendes, Bárbara B.; Zhuang, Yunhui Journal of the American Chemical Society, Vol. 146, Issue 2 https://doi.org/10.1021/jacs.3c12416	journal	January 2024
High Efficiency Adsorption and Removal of Selenate and Selenite from Water Using Metal–Organic Frameworks Howarth, Ashlee J.; Katz, Michael J.; Wang, Timothy C. Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03904	journal	June 2015
Structural Transitions of the Metal-Oxide Nodes within Metal–Organic Frameworks: On the Local Structures of NU-1000 and UiO-66 Platero-Prats, Ana E.; Mavrandonakis, Andreas; Gallington, Leighanne C. Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b00069	journal	March 2016
Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs with Enhanced Tunability Yuan, Shuai; Qin, Jun-Sheng; Zou, Lanfang Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b03263	journal	May 2016
In Situ Probes of Capture and Decomposition of Chemical Warfare Agent Simulants by Zr-Based Metal Organic Frameworks Plonka, Anna M.; Wang, Qi; Gordon, Wesley O. Journal of the American Chemical Society, Vol. 139, Issue 2 https://doi.org/10.1021/jacs.6b11373	journal	January 2017
Metal–Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal–Organic Framework Cliffe, Matthew J.; Castillo-Martínez, Elizabeth; Wu, Yue Journal of the American Chemical Society, Vol. 139, Issue 15 https://doi.org/10.1021/jacs.7b00106	journal	April 2017
Trivalent Zirconium and Hafnium Metal–Organic Frameworks for Catalytic 1,4-Dearomative Additions of Pyridines and Quinolines Ji, Pengfei; Feng, Xuanyu; Veroneau, Samuel S. Journal of the American Chemical Society, Vol. 139, Issue 44 https://doi.org/10.1021/jacs.7b09093	journal	October 2017
Transmission Electron Microscopy Reveals Deposition of Metal Oxide Coatings onto Metal–Organic Frameworks Denny, Michael S.; Parent, Lucas R.; Patterson, Joseph P. Journal of the American Chemical Society, Vol. 140, Issue 4 https://doi.org/10.1021/jacs.7b10453	journal	January 2018
A New Class of Metal-Cyclam-Based Zirconium Metal–Organic Frameworks for CO ₂ Adsorption and Chemical Fixation Zhu, Jie; Usov, Pavel M.; Xu, Wenqian Journal of the American Chemical Society, Vol. 140, Issue 3 https://doi.org/10.1021/jacs.7b10643	journal	January 2018
Charge-Transfer within Zr-Based Metal–Organic Framework: The Role of Polar Node Van Wyk, Andrea; Smith, Tanner; Park, Jaehong Journal of the American Chemical Society, Vol. 140, Issue 8 https://doi.org/10.1021/jacs.7b13211	journal	February 2018
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xPDFsuite: an end-to-end software solution for high throughput pair distribution function transformation, visualization and analysis Yang, Xiaohao; Juhas, Pavol; Farrow, Christopher L. arXiv https://doi.org/10.48550/arXiv.1402.3163	preprint	January 2014
Environmental Contamination by Heavy Metals Masindi, Vhahangwele; Muedi, Khathutshelo L. Heavy Metals https://doi.org/10.5772/intechopen.76082	book	June 2018

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